Naslov
Unseeded, spontaneous nucleation of spherulitic magnesium calcite

Autori
Prus, Marzena ; Li, Chunhui ; Kedra-Krolik, Karolina ; Piasecki, Wojciech ; Lament, Karolina ; Begović, Tajana ; Zarzycki, Piotr

Izvornik
Journal of colloid and interface science (0021-9797) 593 (2021); 359-369

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
Magnesium calcite, Spherulites, Molecular simulations, Solid transformation, Precipitation-dissolution, Growth rate

Sažetak
Most of the sedimentary carbonates deposited in the marine environments are composed of calcium carbonate minerals with varying amounts of incorporated Mg2+. However, understanding how interactions of impurities with carbonate and their incorporation affect sediments behavior remains a challenge. Here, a new insight is obtained by monitoring solution composition, morphology, and electrokinetic potential of carbonate particles formed in a spontaneous unseeded batch precipitation experiment using electrochemical and scanning electron microscopy methods. The solid composition and growth rate are extracted from changes in the bulk composition and fitted to chemical affinity rate law, revealing that the precipitation pathway consists of second-order dissolution and first-order precipitation. The molecular dynamics simulations show that the lattice strain induced by randomly substituting Ca2+ by Mg2+ stabilizes spherical nanoparticles and reduces their surface area and volume. Combining kinetics and thermodynamics insight, we conclude that variation in the carbonate bulk and interfacial energies, along with the solution supersaturation, lead to the dissolution-precipitation transformation pathway from Mg-rich to Mg-poor carbonate phase that preserves spherulitic morphology. Our findings are relevant for long-standing questions of how impurities influence diagenesis of carbonate sediments and spherulitic carbonate particles’ origin.

Izvorni jezik
Engleski

Znanstvena područja
Kemija

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