Pretraga

Pretražite po imenu i prezimenu autora, mentora, urednika, prevoditelja

Napredna pretraga

Pregled bibliografske jedinice broj: 1114231

A ferrocene-based pseudopeptide chiroptical switch

Opačak, Saša; Babić, Darko; Perić, Berislav; Marinić, Željko; Smrečki, Vilko; Pem, Barbara; Vinković Vrček, Ivana; Kirin, Srećko I.
A ferrocene-based pseudopeptide chiroptical switch // Dalton transactions, 13 (2021), 4504-4511 doi:10.1039/D1DT00508A (međunarodna recenzija, članak, znanstveni)

CROSBI ID: 1114231 Za ispravke kontaktirajte CROSBI podršku putem web obrasca

Naslov
A ferrocene-based pseudopeptide chiroptical switch

Autori
Opačak, Saša ; Babić, Darko ; Perić, Berislav ; Marinić, Željko ; Smrečki, Vilko ; Pem, Barbara ; Vinković Vrček, Ivana ; Kirin, Srećko I.

Izvornik
Dalton transactions (1477-9226) 13 (2021); 4504-4511

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
chiroptical switch ; ferrocene ; circular dichroism ; aggregation ; chirality inversion

Sažetak
We present a double-stranded ferrocene pseudopeptide 2b which exhibits stimuli responsive chirality inversion triggered by solvent exchange or acid addition. Compound 2b exists as a mixture of self-assembled fast exchanging oligomers which macroscopically behave as a chiroptical switch with two stable states. The ferrocene group inversion results in a distinct CD signal in the visible part of the spectra. The inversion is accomplished through a conformational change due to a rearrangement of hydrogen bonding forcing the rotation of ferrocene rings.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA

Projekti:
IP-2014-09-1461 - Minimalni umjetni enzimi: Proširenje primjene posredne indukcije na nove supstrate i nove asimetrične reakcije (MArtEn) (Kirin, Srećko, HRZZ - 2014-09) ( CroRIS)
EK-KK.01.1.1.04.0013 - Inovativna rješenja u katalitičkim proizvodnim procesima za potrebe farmaceutske industrije (CAT PHARMA) (Kirin, Srećko, EK ) ( CroRIS)

Ustanove:
Institut za medicinska istraživanja i medicinu rada, Zagreb,
Institut "Ruđer Bošković", Zagreb

Profili:

Avatar Url Barbara Pem (autor)

Avatar Url Darko Babić (autor)

Avatar Url Berislav Perić (autor)

Avatar Url Željko Marinić (autor)

Avatar Url Ivana Vinković Vrček (autor)

Avatar Url Srećko Kirin (autor)

Avatar Url Saša Opačak (autor)

Avatar Url Vilko Smrečki (autor)

Poveznice na cjeloviti tekst rada:

doi pubs.rsc.org doi.org

Citiraj ovu publikaciju:

Opačak, Saša; Babić, Darko; Perić, Berislav; Marinić, Željko; Smrečki, Vilko; Pem, Barbara; Vinković Vrček, Ivana; Kirin, Srećko I.
A ferrocene-based pseudopeptide chiroptical switch // Dalton transactions, 13 (2021), 4504-4511 doi:10.1039/D1DT00508A (međunarodna recenzija, članak, znanstveni)
Opačak, S., Babić, D., Perić, B., Marinić, Ž., Smrečki, V., Pem, B., Vinković Vrček, I. & Kirin, S. (2021) A ferrocene-based pseudopeptide chiroptical switch. Dalton transactions, 13, 4504-4511 doi:10.1039/D1DT00508A.
@article{article, author = {Opa\v{c}ak, Sa\v{s}a and Babi\'{c}, Darko and Peri\'{c}, Berislav and Marini\'{c}, \v{Z}eljko and Smre\v{c}ki, Vilko and Pem, Barbara and Vinkovi\'{c} Vr\v{c}ek, Ivana and Kirin, Sre\'{c}ko I.}, year = {2021}, pages = {4504-4511}, DOI = {10.1039/D1DT00508A}, keywords = {chiroptical switch, ferrocene, circular dichroism, aggregation, chirality inversion}, journal = {Dalton transactions}, doi = {10.1039/D1DT00508A}, volume = {13}, issn = {1477-9226}, title = {A ferrocene-based pseudopeptide chiroptical switch}, keyword = {chiroptical switch, ferrocene, circular dichroism, aggregation, chirality inversion} }
@article{article, author = {Opa\v{c}ak, Sa\v{s}a and Babi\'{c}, Darko and Peri\'{c}, Berislav and Marini\'{c}, \v{Z}eljko and Smre\v{c}ki, Vilko and Pem, Barbara and Vinkovi\'{c} Vr\v{c}ek, Ivana and Kirin, Sre\'{c}ko I.}, year = {2021}, pages = {4504-4511}, DOI = {10.1039/D1DT00508A}, keywords = {chiroptical switch, ferrocene, circular dichroism, aggregation, chirality inversion}, journal = {Dalton transactions}, doi = {10.1039/D1DT00508A}, volume = {13}, issn = {1477-9226}, title = {A ferrocene-based pseudopeptide chiroptical switch}, keyword = {chiroptical switch, ferrocene, circular dichroism, aggregation, chirality inversion} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus
  • MEDLINE

Citati:

    Altmetrijski pokazatelji:


    Podijeli:





    Contrast
    Increase Font
    Decrease Font
    Dyslexic Font
    CROSBI koristi kolačiće (cookies) kako bi poboljšao funkcionalnost stranice.