Pregled bibliografske jedinice broj: 1108745
A new solid-state anionic surfactant-selective sensor based on functionalized MWCNT
A new solid-state anionic surfactant-selective sensor based on functionalized MWCNT // Talanta, 226 (2021), 122196, 10 doi:10.1016/j.talanta.2021.122196 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 1108745 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
A new solid-state anionic surfactant-selective
sensor based on functionalized MWCNT
Autori
Budetić, Mateja ; Samardžić, Mirela ; Ravnjak, Gabriela ; Dandić, Andrea ; Živković, Pavo ; Széchenyi, Aleksandar
Izvornik
Talanta (0039-9140) 226
(2021);
122196, 10
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
multi-walled carbon nanotubes ; anionic surfactants ; potentiometric sensor ; detergents
Sažetak
A new solid-state potentiometric sensor for anionic surfactants (AnS) determination was prepared. The sensor material in the liquid membrane was made of multi-walled carbon nanotubes (MWCNTs) chemically functionalized with a quaternary ammonium group and tetraphenylborate (TPB) anion (MWCNT-N+ (CH3)3TPB-). The response of the MWCNT-N+ (CH3)3TPB- sensor was Nernstian (59.3mV/decade of activity) for both AnS investigated (sodium dodecyl sulfate (NaDDS) and sodium dodecylbenzenesulfonate (DBS)). The limits of detection were 2.0 ∙ 10 -7 and 1.5 ∙ 10 -7 for NaDDS and NaDBS, respectively, and the average response time was only 5 s. The new MWCNT-N+ (CH3)3TPB- sensor was very selective for NaDDS compared to anions usually contained in commercial products and is not affected by nonionic surfactants that can also be present in these products. It was tested to determine AnS concertation by the potentiometric titration method in a pH range between 3 and 12 and successfully applied for its determination in three-component mixtures and real systems.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
EK-KF-KK.01.1.1.01.0010 - Znanstveni centar izvrsnosti za personaliziranu brigu o zdravlju (ZCIPersonHealth) (Polašek, Ozren; Secenji, Aleksandar, EK ) ( CroRIS)
Ustanove:
Sveučilište u Osijeku - Odjel za kemiju
Profili:
Aleksandar Secenji (autor)
Mirela Samardžić (autor)
Pavo Zivkovic (autor)
Andrea Dandić (autor)
Mateja Budetić (autor)
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
- MEDLINE