Pregled bibliografske jedinice broj: 1094853
Morpholine-N-carboxylate as a ligand in coordination chemistry – Syntheses and structures of three heteroleptic copper(II) and zinc complexes
Morpholine-N-carboxylate as a ligand in coordination chemistry – Syntheses and structures of three heteroleptic copper(II) and zinc complexes // Journal of molecular structure, 1205 (2020), 127627, 4 doi:10.1016/j.molstruc.2019.127627 (međunarodna recenzija, članak, znanstveni)
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Naslov
Morpholine-N-carboxylate as a ligand in coordination chemistry – Syntheses and structures of three heteroleptic copper(II) and zinc complexes
Autori
Bedeković, Nikola ; Stilinović, Vladimir
Izvornik
Journal of molecular structure (0022-2860) 1205
(2020);
127627, 4
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
hydrogen bonding, metal chelate
Sažetak
The first three morpholine-N-carboxylate complexes, with copper(II) and zinc(II) have been prepared and studied by single crystal X-ray diffraction. All three compounds comprise of discrete mono- or dinuclear heteroleptic complex molecules. Three different ways of bonding of morphCOOe anions have been observed e as a monodentate, chelating, and as a bridging ligand. In all cases only the carboxyl group of the morpholinecarboxylate anion was found to bind to the metal cation, while the oxygen atom of the morpholine ring participates only in weak CeH‧‧‧O hydrogen bonds. Changes in the geometry of the coordinated morphCOOe anion relative to the free ligand (in its morpholinium salt) were observed in all three modes of binding to the metal center.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Ustanove:
Prirodoslovno-matematički fakultet, Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
