Pregled bibliografske jedinice broj: 1084933
Exapnding the reactivity of a-onium diazoacetates: nucleophilic substitutions with sulfides and a novel route to hydrazonoalkylthioacetates
Exapnding the reactivity of a-onium diazoacetates: nucleophilic substitutions with sulfides and a novel route to hydrazonoalkylthioacetates // 30th Organic chemistry winter meeting of the Norwegian Chemical Society
Lillehammer, Norveška, 2015. str. 25-25 (poster, domaća recenzija, sažetak, znanstveni)
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Naslov
Exapnding the reactivity of a-onium diazoacetates: nucleophilic substitutions with sulfides and a novel route to hydrazonoalkylthioacetates
Autori
Viskić, Marko ; Schnaars, Christian ; Bonge-Hansen, Tore
Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni
Skup
30th Organic chemistry winter meeting of the Norwegian Chemical Society
Mjesto i datum
Lillehammer, Norveška, 08.01.2015. - 11.01.2015
Vrsta sudjelovanja
Poster
Vrsta recenzije
Domaća recenzija
Ključne riječi
alkyldiazoacetate ; nucleophilic addition ; thiols ; diazo compounds
Sažetak
Diazo compounds have great synthetic potential as versatile reagents in both catalytic and non-catalytic carbenoid chemistry. Notorious feature of most -onium diazo compounds is their thermal instability, and a synthetic methodology requiring fine-tuning of mild conditions in various reactions involving a-onium diazoesters is required and has been investigated.1 A series of new a-substituted sulfonium diazoester triflates 2 was prepared by nucleophilic substitution on a-aryliodonium diazoacetate triflate substrate 1 with diverse sulfides.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
