Pregled bibliografske jedinice broj: 1082735
The Morpholinyl Oxygen Atom as an Acceptor Site for Halogen-Bonded Cocrystallization of Organic and Metal–Organic Units
The Morpholinyl Oxygen Atom as an Acceptor Site for Halogen-Bonded Cocrystallization of Organic and Metal–Organic Units // Crystal growth & design, 20 (2020), 6; 3617-3624 doi:10.1021/acs.cgd.0c00520 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 1082735 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
The Morpholinyl Oxygen Atom as an Acceptor Site for Halogen-Bonded Cocrystallization of Organic and Metal–Organic Units
Autori
Nemec, Vinko ; Piteša, Tomislav ; Friščić, Tomislav ; Cinčić, Dominik
Izvornik
Crystal growth & design (1528-7483) 20
(2020), 6;
3617-3624
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
cocrystals ; coordination compounds ; halogen bonding ; morpholine
Sažetak
We explore the halogen bond acceptor potential of the morpholinyl oxygen atom in the synthesis of cocrystals involving organic and metal−organic units, by using N-aminomorpholine either as a potential halogen bond acceptor or as a reagent to insert a morpholine moiety into larger organic and copper(II)-based metal−organic building blocks. Challenged against four well-known halogen bond donor molecules differing in binding geometry and composition, these three morpholine containing units have yielded a total of seven previously not reported cocrystals, of which six (86%) exhibited the formation of I···O or Br···O halogen bonds to the morpholinyl oxygen atom. The results illustrate the possibility to systematically insert and use a morpholine group as an efficient halogen bond acceptor into organic and metal−organic structures, thus enabling cocrystal formation.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
HRZZ-IP-2014-09-7367 - Kristalno inženjerstvo višekomponentinih metaloorganksih materijala povezanih halogenskom vezom: ususret supramolekulskom ugađanju strukture i svojstava (CrystEngMOM) (Cinčić, Dominik, HRZZ - 2014-09) ( CroRIS)
HRZZ-IP-2019-04-1868 - Nove građevne jedinke u supramolekulskom dizajnu složenih višekomponentnih molekulskih kristala temeljenih na halogenskim vezama (HaloBond) (Cinčić, Dominik, HRZZ - 2019-04) ( CroRIS)
Ustanove:
Institut "Ruđer Bošković", Zagreb,
Prirodoslovno-matematički fakultet, Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
