Pregled bibliografske jedinice broj: 1077662
Tetranuclear molybdenum(vi) hydrazonato epoxidation (pre)catalysts: Is water always the best choice?
Tetranuclear molybdenum(vi) hydrazonato epoxidation (pre)catalysts: Is water always the best choice? // Catalysis communications, 142 (2020), 106027-106031 doi:10.1016/j.catcom.2020.106027 (međunarodna recenzija, članak, znanstveni)
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Naslov
Tetranuclear molybdenum(vi) hydrazonato
epoxidation (pre)catalysts: Is water always the
best choice?
Autori
Pisk, Jana ; Agustin, Dominique ; Vrdoljak, Višnja
Izvornik
Catalysis communications (1566-7367) 142
(2020);
106027-106031
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
Tetranuclear molybdenum complexes ; Aroylhydrazones ; Epoxidation ; TBHP inwater and decane ; No organic solvent added
Sažetak
Self-assembled tetranuclear molybdenum(vi) complexes with hydrazonato ligands, [MoO2L]4, were tested as (pre)catalysts for cyclooctene and cyclohexene epoxidation without extra organic solvent added. Special attention was addressed to the comparison of oxidizing agents, TBHP in water vs. TBHP in decane. The idea was to test the greenness of the complete process. Density Functional Theory calculations were used to support and explain experimental catalytic result for tetranuclear self- assembled systems.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
HRZZ-IP-2016-06-4221 - Metalosupramolekulske strukture i anorgansko-organski polioksometalatni hibridi (MOLART) (Vrdoljak, Višnja, HRZZ - 2016-06) ( CroRIS)
Ustanove:
Prirodoslovno-matematički fakultet, Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
