Naslov
A novel nitroprusside association complex with the pharmacologically important ligand: crystal structure and supramolecular assembly

Autori
Furač, Ivana ; Foretić, Blaženka

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, stručni

Izvornik
III. simpozij supramolukulske kemije = Supramolecular chemistry 2019 : knjiga sažetaka / Frkanec, Leo ; Namjesnik, Danijel ; Tomišić, Vladislav - Zagreb : Institut Ruđer Bošković, 2019, 30-30

ISBN
978-953-7941-27-7

Skup
3. simpozij supramolekulske kemije (Supramolecular Chemistry 2019)

Mjesto i datum
Zagreb, Hrvatska, 03.12.2019

Vrsta sudjelovanja
Poster

Vrsta recenzije
Domaća recenzija

Ključne riječi
nitroprusside ; toxogonin ; crystal structure

Sažetak
Nitroprussides (pentacyanonitrosylferrate(II) anions, [Fe(CN)5NO]2) are emerging as novel materials with promising applications in diverse molecular communication and for storage information devices. Reaction between photochromic nitroprusside anion and the bis-pyridinium-4-oxime cation of Toxogonin (TOXO-2Cl) in the water results in spontaneous formation of association compound. This complex crystallize in the triclinic system, space group P -1. The asymmetric unit contains one TOXO2+ cation, one [Fe(CN)5NO]2– anion and water molecules of crystallization. These mutual interactions and the water hydrogen bonding link the ions and molecules into layered 2D structures of formula unit TOXO[Fe(CN)5NO]. Herein, we report the structural, spectroscopic (Mössbauer, FT-IR, solid UV-VIS) and thermal characterization of this novel complex compound.

Izvorni jezik
Engleski

Znanstvena područja
Temeljne medicinske znanosti

POVEZANOST RADA