Pregled bibliografske jedinice broj: 1029159
A Brief Review on the Use of Chelation Agents in Sol-gel Synthesis with Emphasis on β-Diketones and β-Ketoesters
A Brief Review on the Use of Chelation Agents in Sol-gel Synthesis with Emphasis on β-Diketones and β-Ketoesters // Chemical and biochemical engineering quarterly, 33 (2019), 295-301 (međunarodna recenzija, pregledni rad, znanstveni)
CROSBI ID: 1029159 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
A Brief Review on the Use of Chelation Agents in Sol-gel Synthesis with Emphasis on β-Diketones and β-Ketoesters
Autori
Kurajica, Stanislav
Izvornik
Chemical and biochemical engineering quarterly (0352-9568) 33
(2019);
295-301
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, pregledni rad, znanstveni
Ključne riječi
alkoxides ; chelation ; FTIR ; NMR ; sol-gel
Sažetak
Metal alkoxides are the most commonly used sol-gel process precursors. Most alkoxides show excessive reactivity towards water. That leads to rapid hydrolysis, metal hydroxide formation, and immediate precipitation. The reactivity of alkoxides can be reduced by modification with chelation agents. Chelation influences the gelation process, which is reflected in gel structure and properties of the final material. In this short review, the chelation process, the oligomerization phenomena, and the influence of the chelating agent on the gel structure are discussed. Peculiarities of the use of FTIR and NMR, as methods particularly suitable for the investigation of chelation process, are described taking ethyl acetoacetate as an example.
Izvorni jezik
Engleski
Znanstvena područja
Kemija, Kemijsko inženjerstvo, Temeljne tehničke znanosti
POVEZANOST RADA
Projekti:
HRZZ-IP-2018-01-2963 - Hidrotermalna sinteza dopiranog cerij oksidnog nanokatalizatora (HOuDiNI) (Kurajica, Stanislav, HRZZ - 2018-01) ( CroRIS)
Ustanove:
Fakultet kemijskog inženjerstva i tehnologije, Zagreb
Profili:
Stanislav Kurajica
(autor)
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus