Naslov
CeO2 Wetting Layer on ZrO2 Particle with Sharp Solid Interface as Highly Active and Stable Catalyst for HCl Oxidation Reaction

Autori
Sun, Yu ; Cop, Pascal ; Djerdj, Igor ; Guo, Xiaohan ; Weber, Tim ; Khalid, Omeir ; Guo, Yanglong ; Smarsly, Bernd M. ; Over, Herbert

Izvornik
ACS Catalysis (2155-5435) 9 (2019), 12; 10680-10693

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
dry impregnation ; layered catalysts ; ceria ; zirconia

Sažetak
Dry impregnation of CeO2 on ZrO2 particles (CeO2@ZrO2) and calcination at 600 °C for 5 h results in a highly dispersed layer of the catalytically active phase CeO2 with an enriched concentration of Ce3+. The distinct morphology of CeO2@ZrO2 is responsible for the high (specific) activity in the gas-phase oxidation of HCl (Deacon reaction). Surprisingly, the CeO2@ZrO2 catalyst calcined at 600 ºC is chemically even more stable towards chlorination under harsh Deacon conditions than that calcined at 900 °C, where a solid solution of ZrO2 and CeO2 is formed at the solid interface. The improved stability of the CeO2 layer calcined at 600 ºC is traced to its sharp interface formed with ZrO2 support. We expect that this kind of active and stable layer morphology of CeO2 on ZrO2 is beneficial for other catalytic oxidation reaction as well, either as active component or as supporting material for another active metal component.

Izvorni jezik
Engleski

Znanstvena područja
Fizika, Kemija

POVEZANOST RADA