Naslov
Magneto-structural correlation in Cu(II) complexes with iPr-bpa studied by ESR spectroscopy

Autori
Muratović, Senada ; Žilić, Dijana ; Pantalon Juraj, Natalija ; Perić, Berislav ; Kirin, Srećko I.

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
Solid-State Science & Research 2019 - Book of Abstracts / Biliškov, Nikola - Zagreb : Institut Ruđer Bošković, 2019, 104-104

ISBN
978-953-7941-32-1

Skup
Solid State Science and Research Meeting

Mjesto i datum
Zagreb, Hrvatska, 27.06.2019. - 29.06.2019

Vrsta sudjelovanja
Poster

Vrsta recenzije
Domaća recenzija

Ključne riječi
Copper(II) complexes ; ESR spectroscopy

Sažetak
Reaction of the bis(2-picolyl)amine (bpa) ligand with copper(II) results in formation of four complexes with a large structural variety: monomer, bromo-bridged dimer, a coordination polymer and a cyclic trimer that binds atmospheric CO2. Here we present an X-band electron spin resonance (ESR) study of the copper(II) complexes, from room down to liquid helium temperature. The spectral simulations were obtained using spin-Hamiltonian approach and EasySpin software [1]. The results obtained from the study will be discussed in terms of copper coordination geometries and magnetic interactions of copper spins S = 1/2 [2, 3].

Izvorni jezik
Engleski

Znanstvena područja
Fizika, Kemija

POVEZANOST RADA