Naslov
Steric and electronic effects in formation of co- crystals in solid-state and their sustainability in solution

Autori
Mišura, Ozana ; Pisačić, Mateja ; Đaković, Marijana

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
Solid-State Science & Research 2019 : book of abstracts / Biliškov, Nikola - Zagreb : Institut Ruđer Bošković, 2019, 92-92

ISBN
978-953-7941-32-1

Skup
Solid State Science and Research Meeting

Mjesto i datum
Zagreb, Hrvatska, 27.06.2019. - 29.06.2019

Vrsta sudjelovanja
Poster

Vrsta recenzije
Međunarodna recenzija

Ključne riječi
coordination polymers ; co-crystals ; cadmium(II) ; electronic effects

Sažetak
Crystal engineering is today a preferable approach to synthesis of molecular solids of targeted supramolecular connectivities and desired topologies. Unfortunately, going from molecular to supramolecular structure is still not a very straightforward path. A complete understanding of relations between molecular structure and intermolecular interactions, i.e. how small and controllable changes in molecular structure (manipulation of steric, geometric, and electronic effects) can influence intermolecular interactions is still needed, and it will enable us to build desired supramolecular solid-state architectures. In order to investigate the role of electronic and steric effects in formation of co-crystals in solid-state and their sustainability in solution, several coformers were combined with cadmium(II) coordination compounds. The syntheses were performed by liquid-assisted grinding and resulting co-crystal products were confirmed with PXRD experiments. Given the intention to determine crystal structure, each of co-crystal was dissolved in several solvents to provide single crystals. It has been observed that in those solvents some co-crystals are not preserved which was correlated with electronic effects.

Izvorni jezik
Engleski

Znanstvena područja
Kemija

POVEZANOST RADA