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Organic Salts and Merrifield Resin Supported [PM12O40]3− (M = Mo or W) as Catalysts for Adipic Acid Synthesis (CROSBI ID 262126)

Prilog u časopisu | izvorni znanstveni rad | međunarodna recenzija

Pisk, Jana ; Agustin, Dominique ; Poli, Rinaldo Organic Salts and Merrifield Resin Supported [PM12O40]3− (M = Mo or W) as Catalysts for Adipic Acid Synthesis // Molecules, 24 (2019), 4; 783, 15. doi: 10.3390/molecules24040783

Podaci o odgovornosti

Pisk, Jana ; Agustin, Dominique ; Poli, Rinaldo

engleski

Organic Salts and Merrifield Resin Supported [PM12O40]3− (M = Mo or W) as Catalysts for Adipic Acid Synthesis

Adipic acid (AA) was obtained by catalyzed oxidation of cyclohexene, epoxycyclohexane, or cyclohexanediol under organic solvent-free conditions using aqueous hydrogen peroxide (30%) as an oxidizing agent and molybdenum- or tungsten-based Keggin polyoxometalates (POMs) surrounded by organic cations or ionically supported on functionalized Merrifield resins. Operating under these environmentally friendly, greener conditions and with low catalyst loading (0.025% for the molecular salts and 0.001–0.007% for the supported POMs), AA could be produced in interesting yields.

polyoxometalates ; Merrifield resin ; cyclohexene ; adipic acid ; organic solvent-free process

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Podaci o izdanju

24 (4)

2019.

783

15

objavljeno

1420-3049

10.3390/molecules24040783

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