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Pregled bibliografske jedinice broj: 984806

Magnetic field influence on asphaltene aggregation monitored by diffusion NMR spectroscopy: Is aggregation reversible at high magnetic fields?


Parlov Vuković, Jelena; Novak, Predrag; Jednačak, Tomislav; Kveštak, Martina; Kovačević, Davor; Smrečki, Vilko; Mikulandra, Ivana; Djetelić Ibrahimpašić, Mateja; Glanzer, Simon; Zangger, Klaus
Magnetic field influence on asphaltene aggregation monitored by diffusion NMR spectroscopy: Is aggregation reversible at high magnetic fields? // Journal of dispersion science and technology, 40 (2019), 8; 1-9 doi:10.1080/01932691.2018.1561302 (međunarodna recenzija, članak, znanstveni)


Naslov
Magnetic field influence on asphaltene aggregation monitored by diffusion NMR spectroscopy: Is aggregation reversible at high magnetic fields?

Autori
Parlov Vuković, Jelena ; Novak, Predrag ; Jednačak, Tomislav ; Kveštak, Martina ; Kovačević, Davor ; Smrečki, Vilko ; Mikulandra, Ivana ; Djetelić Ibrahimpašić, Mateja ; Glanzer, Simon ; Zangger, Klaus

Izvornik
Journal of dispersion science and technology (0193-2691) 40 (2019), 8; 1-9

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
Asphaltenes ; aggregation ; DOSY NMR ; convection currents ; magnetic field dependence

Sažetak
We have shown that asphaltene self-association induces temperature gradients and convection currents and it is necessary to suppress these effects to obtain accurate data by DOSY NMR techniques. An interesting finding of this investigation is that aggregation process has been found to be affected by the magnetic field. The obtained results have shown for the first time a significant increase in diffusion coefficients of aggregates upon the increase in the magnetic field strength indicating higher molecular mobility of the present species and possible degradation of aggregates. We have shown that changes in diffusion coefficients are not a consequence of relaxation or viscosity effects. It is not yet clear what the reason for such behavior is and whether this effect is intrinsic. Traces of paramagnetic metals present in asphaltene samples may play a role in this process but this hypothesis is yet to be explored. Furthermore, this study has revealed a similar concentration range in which the Middle East crude oil asphaltenes aggregate being in agreement with previous results. Aggregates form different molecular weight species with different composition and number of monomer units. Ongoing experiments will throw more light on the magnetic field dependent asphaltene aggregation. This may have an impact on developing strategies for resolving asphaltene precipitation issues.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Ustanove
Institut "Ruđer Bošković", Zagreb,
Prirodoslovno-matematički fakultet, Zagreb

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus


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