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Pregled bibliografske jedinice broj: 980969

Isotope Labeling Reveals Fast Atomic and Molecular Exchange in Mechanochemical Milling Reactions


Lukin, Stipe; Tireli, Martina; Stolar, Tomislav; Barišić, Dajana; Blanco, Maria Valeria; di Michiel, Marco; Užarević, Krunoslav; Halasz, Ivan
Isotope Labeling Reveals Fast Atomic and Molecular Exchange in Mechanochemical Milling Reactions // Journal of the American Chemical Society, 141 (2019), 3; 1212-1216 doi:10.1021/jacs.8b12149 (međunarodna recenzija, članak, znanstveni)


CROSBI ID: 980969 Za ispravke kontaktirajte CROSBI podršku putem web obrasca

Naslov
Isotope Labeling Reveals Fast Atomic and Molecular Exchange in Mechanochemical Milling Reactions

Autori
Lukin, Stipe ; Tireli, Martina ; Stolar, Tomislav ; Barišić, Dajana ; Blanco, Maria Valeria ; di Michiel, Marco ; Užarević, Krunoslav ; Halasz, Ivan

Izvornik
Journal of the American Chemical Society (0002-7863) 141 (2019), 3; 1212-1216

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
isotope labeling ; mechanochemistry ; mechanochemical deuteration ; in situ monitoring ; solid-state diffusion ; H/D exchange

Sažetak
Using tandem in situ monitoring and isotope- labeled solids, we reveal that mechanochemical ball-milling overcomes inherently slow solid- state diffusion through continuous comminution and growth of milled particles. This process occurs with or without a net chemical reaction and also occurs between solids and liquid additives that can be practically used for highly efficient deuterium labeling of solids. The presented findings reveal a fundamental aspect of milling reactions and also delineate a methodology that should be considered in the study of mechanochemical reaction mechanisms.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekt / tema
HRZZ-UIP-2014-09-4744 - Mehaniokemijska reaktivnost pod kontroliranim uvjetima temperature i atmosfere za čišću sintezu funkcionalnih materijala (Krunoslav Užarević, )

Ustanove
Institut "Ruđer Bošković", Zagreb

Citiraj ovu publikaciju

Lukin, Stipe; Tireli, Martina; Stolar, Tomislav; Barišić, Dajana; Blanco, Maria Valeria; di Michiel, Marco; Užarević, Krunoslav; Halasz, Ivan
Isotope Labeling Reveals Fast Atomic and Molecular Exchange in Mechanochemical Milling Reactions // Journal of the American Chemical Society, 141 (2019), 3; 1212-1216 doi:10.1021/jacs.8b12149 (međunarodna recenzija, članak, znanstveni)
Lukin, S., Tireli, M., Stolar, T., Barišić, D., Blanco, M., di Michiel, M., Užarević, K. & Halasz, I. (2019) Isotope Labeling Reveals Fast Atomic and Molecular Exchange in Mechanochemical Milling Reactions. Journal of the American Chemical Society, 141 (3), 1212-1216 doi:10.1021/jacs.8b12149.
@article{article, year = {2019}, pages = {1212-1216}, DOI = {10.1021/jacs.8b12149}, keywords = {isotope labeling, mechanochemistry, mechanochemical deuteration, in situ monitoring, solid-state diffusion, H/D exchange}, journal = {Journal of the American Chemical Society}, doi = {10.1021/jacs.8b12149}, volume = {141}, number = {3}, issn = {0002-7863}, title = {Isotope Labeling Reveals Fast Atomic and Molecular Exchange in Mechanochemical Milling Reactions}, keyword = {isotope labeling, mechanochemistry, mechanochemical deuteration, in situ monitoring, solid-state diffusion, H/D exchange} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus
  • MEDLINE


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