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Pregled bibliografske jedinice broj: 964968

The impact of dextran sulfate on the radiolytic synthesis of magnetic iron oxide nanoparticles


Jurkin, Tanja; Marić, Ivan; Štefanić, Goran; Gotić, Marijan
The impact of dextran sulfate on the radiolytic synthesis of magnetic iron oxide nanoparticles // Book of Abstracts of the XXXIV European Congress on Molecular Spectroscopy / Fausto, Rui ; Bras, Elisa ; Justino, Licinia ; Nogueira, Bernardo (ur.).
Coimbra, Portugal: Department of Chemistry, University of Coimbra, 2018. str. 253-253 (poster, međunarodna recenzija, sažetak, znanstveni)


CROSBI ID: 964968 Za ispravke kontaktirajte CROSBI podršku putem web obrasca

Naslov
The impact of dextran sulfate on the radiolytic synthesis of magnetic iron oxide nanoparticles

Autori
Jurkin, Tanja ; Marić, Ivan ; Štefanić, Goran ; Gotić, Marijan

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
Book of Abstracts of the XXXIV European Congress on Molecular Spectroscopy / Fausto, Rui ; Bras, Elisa ; Justino, Licinia ; Nogueira, Bernardo - Coimbra, Portugal : Department of Chemistry, University of Coimbra, 2018, 253-253

ISBN
978-989-20-8611-8

Skup
XXXIV - European Congress on Molecular Spectroscopy - EUCMOS 2018

Mjesto i datum
Coimbra, Portugal, 19 - 24. 08. 2018

Vrsta sudjelovanja
Poster

Vrsta recenzije
Međunarodna recenzija

Ključne riječi
iron oxides ; gamma-irradiation ; dextran sulfate ; green rust ; iron(II) hydroxide ; feroxyhyte

Sažetak
Recently, the new synthesis route to delta-FeOOH nanodiscs based on the γ-irradiation of a deoxygenated iron(III) chloride alkaline aqueous colloidal solution in the presence of diethylaminoethyl-dextran hydrochloride (DEAE-dextran) has been reported by Jurkin et al. [1]. In that work we supposed that γ-irradiation produced reducing conditions and that delta-FeOOH nanoparticles were formed through oxidation of obtained white suspension characteristic of Fe(OH)2. In this work, we studied the impact of dextran sulfate polymer (DEX-sulfate) on the radiolytic synthesis of magnetic iron oxide nanoparticles. The syntheses started with γ-irradiation (130 kGy) of deoxygenated iron(III) chloride alkaline aqueous colloidal solution in the presence of 2-propanol and DEX-sulfate. The radiolytically synthesised samples were isolated by conventional process of sample isolation (centrifugation/washing with water or ethanol) or in the presence of glycerol. The XRD results showed that sample isolated in the presence of glycerol contained Fe(OH)2, hydroxysulfate green rust II (GR SO42-) and goethite (alfa-FeOOH). The Mössbauer results confirmed the presence of Fe(OH)2 and hydroxysulfate green rust II (GR SO42-) in this sample. The radiolytically synthesized samples that were isolated by centrifugation and washing with water or ethanol contained GR SO42- and alfa-Fe2O3. Therefore, the DEX-sulfate favoured the formation of alfa-FeOOH and/or alfa-Fe2O3 through GR-II (SO42-) intermediate product.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekti:
HRZZ-UIP-2017-05-7337 - Utjecaj polimera na radiolitičku sintezu magnetskih nanočestica (POLRADNANOP) (Jurkin, Tanja, HRZZ - 2017-05) ( POIROT)

Ustanove:
Institut "Ruđer Bošković", Zagreb

Profili:

Avatar Url Marijan Gotić (autor)

Avatar Url Tanja Jurkin (autor)

Avatar Url Goran Štefanić (autor)

Avatar Url Ivan Marić (autor)

Poveznice na cjeloviti tekst rada:

www.qui.uc.pt

Citiraj ovu publikaciju:

Jurkin, Tanja; Marić, Ivan; Štefanić, Goran; Gotić, Marijan
The impact of dextran sulfate on the radiolytic synthesis of magnetic iron oxide nanoparticles // Book of Abstracts of the XXXIV European Congress on Molecular Spectroscopy / Fausto, Rui ; Bras, Elisa ; Justino, Licinia ; Nogueira, Bernardo (ur.).
Coimbra, Portugal: Department of Chemistry, University of Coimbra, 2018. str. 253-253 (poster, međunarodna recenzija, sažetak, znanstveni)
Jurkin, T., Marić, I., Štefanić, G. & Gotić, M. (2018) The impact of dextran sulfate on the radiolytic synthesis of magnetic iron oxide nanoparticles. U: Fausto, R., Bras, E., Justino, L. & Nogueira, B. (ur.)Book of Abstracts of the XXXIV European Congress on Molecular Spectroscopy.
@article{article, author = {Jurkin, Tanja and Mari\'{c}, Ivan and \v{S}tefani\'{c}, Goran and Goti\'{c}, Marijan}, year = {2018}, pages = {253-253}, keywords = {iron oxides, gamma-irradiation, dextran sulfate, green rust, iron(II) hydroxide, feroxyhyte}, isbn = {978-989-20-8611-8}, title = {The impact of dextran sulfate on the radiolytic synthesis of magnetic iron oxide nanoparticles}, keyword = {iron oxides, gamma-irradiation, dextran sulfate, green rust, iron(II) hydroxide, feroxyhyte}, publisher = {Department of Chemistry, University of Coimbra}, publisherplace = {Coimbra, Portugal} }
@article{article, author = {Jurkin, Tanja and Mari\'{c}, Ivan and \v{S}tefani\'{c}, Goran and Goti\'{c}, Marijan}, year = {2018}, pages = {253-253}, keywords = {iron oxides, gamma-irradiation, dextran sulfate, green rust, iron(II) hydroxide, feroxyhyte}, isbn = {978-989-20-8611-8}, title = {The impact of dextran sulfate on the radiolytic synthesis of magnetic iron oxide nanoparticles}, keyword = {iron oxides, gamma-irradiation, dextran sulfate, green rust, iron(II) hydroxide, feroxyhyte}, publisher = {Department of Chemistry, University of Coimbra}, publisherplace = {Coimbra, Portugal} }




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