engleski

Simultaneous Determination of Six Inorganic Anions in Drinking Water by Non - Suppressed Ion Chromatography

The non – suppressed ion chromatographic method with conductometric detection is described for simultaneous determination of six inorganic anions: fluoride, chloride, nitrite, bromide, nitrate and sulphate. The separation was achieved on a low capacity anion exchange column Metrohm IC Anion Column Super Sep, with a mobile phase consisted of phtalic acid dissolved in high purity water, 2-amino-2-hydroxymethyl-1, 3-propendiol and acetonitrile. In this work computer optimization procedures, using computer programs to select chromatographic conditions have been used, leading to the achievement of a desired separation. By using the different optimization methods in an integrated manner it is, however, possible both to speed method development, by reducing unnecessary experimentation, and to overcome many of shortcomings of each method, because of the different approaches. The purpose of this work is to improve and characterise the method for simultaneous determination of six inorganic anions in drinking water by non - suppressed ion chromatography, using optimization procedures, in order to be applied to the routine analysis. The proposed method has numerous advantages over the others widely used non - suppressed ion chromatography methods: higher selectivity, shorter analysis time, lower quantitation and detection limits. The performance characteristics of the method were established by determining following validation parameters: precision and accuracy, linearity, detection limits and quantitation limits.

ion chromatography ; water analysis ; inorganic anions ; optimization

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