engleski

Tetra-μ-benzoato-κ8O:O'-bis[N, N'-diethylformamide-κO)dicopper(II)

Copper(II) carboxylates are based on a robust dinuclear paddlewheel unit to which additional ligands are attached by coordinating at the apical positions. Their simple syntheses have made copper(II) carboxylates interesting for materials science, especially for constructing porous metal–organic frameworks. The ability of such molecules to form adducts through binding additional ligands, in one application leads to formation of metal-containing frameworks (MOFs). By reacting the N, N'-diethylformamide and tetra-μ-benzoato-κ8O:O'-dicopper(II) complexes we have succeded to isolate and determine the crystal and molecular structures of the tetra-μ-benzoato-κ8O:O'-bis[(N, N'-diethylformamide-κO)dicopper(II)] The structure of the compounds suggest guidelines to achieve supramolecular isostructurality, useful for the synthesis of multi-component metal-organic materials following a design based on solid solution.

copper complex

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