engleski

Combined Mechanocemical and solution shyntesis of Copper(II) Carboxylates

Synthesis of paddlewheel complexes is not demanding and their abbility to bind various ligands makes them eligible building blocks in crystal engineering and preparing metal-organic frameworks. CSD contains suprisingly small number of non-acetato or benzoato copper(II) paddlewheels. We decided to search for new carboxylato coppr(II) complexes by combining mechanochemical and solution synthesis. Our results are promising and provided us with several single crystal specimens for which we solved their crystal and molecular structures. Our results indicate a good potential for synthesis of various paddlewheels in situ and corresponingly more targeted multicomponent supramolecular networks that contain metal ions should be obtained.

copper complex

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