Napredna pretraga

Pregled bibliografske jedinice broj: 950784

Tuning the Reactivity of Peroxo Anhydrides for Aromatic C–H Bond Oxidation


Pilevar, Afsaneh; Hosseini, Abolfazl; Šekutor, Marina; Hausmann, Heike; Becker, Jonathan; Turke, Kevin; Schreiner, Peter R.
Tuning the Reactivity of Peroxo Anhydrides for Aromatic C–H Bond Oxidation // Journal of organic chemistry, 83 (2018), 10070-10079 doi:10.1021/acs.joc.8b01392 (međunarodna recenzija, članak, znanstveni)


Naslov
Tuning the Reactivity of Peroxo Anhydrides for Aromatic C–H Bond Oxidation

Autori
Pilevar, Afsaneh ; Hosseini, Abolfazl ; Šekutor, Marina ; Hausmann, Heike ; Becker, Jonathan ; Turke, Kevin ; Schreiner, Peter R.

Izvornik
Journal of organic chemistry (0022-3263) 83 (2018); 10070-10079

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
Cyclic peroxide, C-H oxidation, hydroxylation of arenes, norbornane

Sažetak
Phenol moieties are key structural motifs in many areas of chemical research from polymers to pharmaceuticals. Herein, we report on the design and use of a structurally demanding cyclic peroxide (spiro[bicyclo[2.2.1]heptane-2, 4′-[1, 2]dioxolane]-3′, 5′-dione, P4) for the direct hydroxylation of aromatic substrates. The new peroxide benefits from high thermal stability and can be synthesized from readily available starting materials. The aromatic C–H oxidation using P4 exhibits generally good yields (up to 96%) and appreciable regioselectivities.

Izvorni jezik
Engleski

Znanstvena područja
Kemija

Napomena
This work was supported by Justus Liebig University.



POVEZANOST RADA


Autor s matičnim brojem:
Marina Šekutor, (312901)

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • Arts & Humanities Citation Index (A&HCI)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus
  • MEDLINE


Citati