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Concentration dependence of asphaltene aggregation monitored by DOSY NMR


Mikulandra, Ivana; Jednačak, Tomislav; Parlov Vuković, Jelena; Djetelić Ibrahimpašić, Mateja; Zangger, Klaus; Smrečki, Vilko; Novak, Predrag
Concentration dependence of asphaltene aggregation monitored by DOSY NMR // Book of abstracts / Bregović, Nikola ; Namjesnik, Danijel ; Novak, Predrag ; Pičuljan, Katarina (ur.).
Zagreb: Department of Chemistry, Faculty of Science, University of Zagreb, Croatia, 2018. str. 57-57 (poster, nije recenziran, sažetak, znanstveni)


Naslov
Concentration dependence of asphaltene aggregation monitored by DOSY NMR

Autori
Mikulandra, Ivana ; Jednačak, Tomislav ; Parlov Vuković, Jelena ; Djetelić Ibrahimpašić, Mateja ; Zangger, Klaus ; Smrečki, Vilko ; Novak, Predrag

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
Book of abstracts / Bregović, Nikola ; Namjesnik, Danijel ; Novak, Predrag ; Pičuljan, Katarina - Zagreb : Department of Chemistry, Faculty of Science, University of Zagreb, Croatia, 2018, 57-57

ISBN
978-953-6076-42-0

Skup
Adriatic NMR conference

Mjesto i datum
Mali Ston, Hrvatska, 15-17.06.2018

Vrsta sudjelovanja
Poster

Vrsta recenzije
Nije recenziran

Ključne riječi
Asphaltene aggregation ; diffusion coefficients ; DOSY NMR spectroscopy

Sažetak
Asphaltenes are the heaviest, most polar and least reactive molecules in crude oil, primarily consisting of carbons and hydrogens, some heteroatoms, such as sulfur, nitrogen, oxygen and traces of transition metals. They may aggregate during the downstream and upstream processes and cause many problems in production, refining and transportation. Asphaltene aggregation highly depends on the chemical nature of the crude oil, temperature and pressure. In this research, concentration dependent diffusion measurements were carried out to determine the lowest aggregation concentration of Middle Eastern asphaltenes and to study how the addition of V(IV), Fe(III) and Ni(II) affects the aggregation process. Asphaltene components were separated by DOSY NMR technique according to their diffusion properties. The influence of T1 relaxation on average diffusion coefficients was investigated by inversion recovery experiments. Changes in diffusion coefficients reflected the formation of different asphaltene types. It is expected that the presented results could throw more light into the asphaltene aggregation mechanism.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Ustanove
Prirodoslovno-matematički fakultet, Zagreb