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Pregled bibliografske jedinice broj: 938672

Synthesis and Anion Binding Assessment of Novel Adamantane Amidopyrroles


Alešković, Marija; Glavaš, Mladena; Šekutor, Marina; Mlinarić-Majerski, Kata
Synthesis and Anion Binding Assessment of Novel Adamantane Amidopyrroles // Croatica chemica acta, 90 (2017), 4; 637-643 doi:10.5562/cca3248 (međunarodna recenzija, članak, znanstveni)


Naslov
Synthesis and Anion Binding Assessment of Novel Adamantane Amidopyrroles

Autori
Alešković, Marija ; Glavaš, Mladena ; Šekutor, Marina ; Mlinarić-Majerski, Kata

Izvornik
Croatica chemica acta (0011-1643) 90 (2017), 4; 637-643

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
Anion receptors, adamantane amidopyrroles, binding assessment

Sažetak
Two new adamantane anion receptors with amidopyrrole side arms were prepared and their anion binding ability in DMSO solutions with TBA salts (Cl–, AcO– and H2PO4–) was investigated by UV/Vis spectroscopy. After calculating the corresponding association constants of receptor-anion complexes, it became apparent that only one amidopyrrole side arm was engaged in complexation. These experimental findings were rationalized using computational tools and the binding mode was proposed. In addition to the found 1 : 1 stoichiometry, we showed that the studied receptors bind oxo-anions (H2PO4– and AcO–) more strongly than spherical halogenide (Cl–) anions.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekt / tema
098-0982933-2911 - Kavezasti spojevi: ugradbene jedinice u molekularnim sustavima (Kata Majerski, )

Ustanove
Institut "Ruđer Bošković", Zagreb

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus


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