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Cooperativity in Binding of Aliphatic Diamines by Bis(Zn(II)porphyrin) Receptor with Moderately Flexible Linkers


Briš, Anamarija; Trošelj, Pavle; Margetić, Davor
Cooperativity in Binding of Aliphatic Diamines by Bis(Zn(II)porphyrin) Receptor with Moderately Flexible Linkers // Croatica chemica acta, 90 (2017), 4; 667-677 doi:10.5562/cca3249 (međunarodna recenzija, članak, znanstveni)


Naslov
Cooperativity in Binding of Aliphatic Diamines by Bis(Zn(II)porphyrin) Receptor with Moderately Flexible Linkers

Autori
Briš, Anamarija ; Trošelj, Pavle ; Margetić, Davor

Izvornik
Croatica chemica acta (0011-1643) 90 (2017), 4; 667-677

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
Host-guest interactions ; supramolecular chemistry ; bis-porphyrin ; complexation ; binding constant ; UV-Vis

Sažetak
Complexations of bis(Zn(II)porphyrin) receptor possessing moderately flexible linkers with aliphatic α, ω-diamines was studied by UV-vis and NMR spectroscopy. The strongest binding was identified for 1, 8-diaminooctane, with the binding constant by one order of the magnitude larger than the next diamine homologue 1, 7-diaminoheptane.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekt / tema
098-0982933-3218 - 'Host-guest' međudjelovanja u policikličkim sustavima (Davor Margetić, )
HRZZ-IP-2013-11-9310 - Nekovalentne interakcije u dizajnu novih fotoosjetljivih molekula (Davor Margetić, )

Ustanove
Institut "Ruđer Bošković", Zagreb

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus


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