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Nitranilic acid: a versatile ligand for design of novel coordination polymers (CROSBI ID 661437)

Prilog sa skupa u zborniku | sažetak izlaganja sa skupa

Milašinović, Valentina ; Molčanov, Krešimir Nitranilic acid: a versatile ligand for design of novel coordination polymers // Chemistry Conference for Young Scientists : Book of abstracts. 2018. str. 124-124

Podaci o odgovornosti

Milašinović, Valentina ; Molčanov, Krešimir

engleski

Nitranilic acid: a versatile ligand for design of novel coordination polymers

Nitranilic acid (2, 5-dihydroxy-3, 5-dinitroquinone, (NA)) is a quinoid compound capable of acting as a bridging bis(bidentate) ligand. However, it has been surprisingly little studied and only a few of its metal complexes have been known. We have prepared and structurally characterised five novel coordination polymers of nitranilic acid with different topologies. Compounds [Co(NA)(H2O)2]n and [Cu(NA)(H2O)2]n are isostructural and are 1D zig-zag polymers analogous to similar complexes of chloranilic acid (Fig 1a). Anionic polymer [Ag(NA)]-n crystallises as a salt with dimethylammonium cation and displays a novel 1D motive of double chains (Fig 1b). Complex [Ag2(NA)]n has a 3D network (Fig 1c). This study shows that the nitranilic acid has a great potential for design of coordination polymers or metal-organic frameworks.

Nitranilna kiselina ; kinon ; koordinacijski polimer

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Podaci o prilogu

124-124.

2018.

objavljeno

Podaci o matičnoj publikaciji

Chemistry Conference for Young Scientists : Book of abstracts

Podaci o skupu

Chemistry Conference for Young Scientists

predavanje

21.02.2018-23.02.2018

Blankenberge, Belgija

Povezanost rada

Kemija