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Induced smectic phase in binary mixture of twist- bend nematogens


Knežević, Anamarija; Dokli, Irena; Sapunar, Marin; Šegota, Suzana; Baumeister, Ute; Lesac, Andreja
Induced smectic phase in binary mixture of twist- bend nematogens // Beilstein Journal of Nanotechnology, 9 (2018), 1297, 11 doi:10.3762/bjnano.9.122 (međunarodna recenzija, članak, znanstveni)


Naslov
Induced smectic phase in binary mixture of twist- bend nematogens

Autori
Knežević, Anamarija ; Dokli, Irena ; Sapunar, Marin ; Šegota, Suzana ; Baumeister, Ute ; Lesac, Andreja

Izvornik
Beilstein Journal of Nanotechnology (2190-4286) 9 (2018); 1297, 11

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
Binary mixture, liquid crystals, smectic phase induction, temperature-dependent FT-IR, twist-bend nematogen

Sažetak
The investigation of liquid crystal (LC) mixtures is of great interest in tailoring material properties for specific applications. The recent discovery of the twist-bend nematic phase (NTB) has sparked great interest in the scientific community, not only from a fundamental viewpoint, but also due to its potential for innovative applications. Here we report on the unexpected phase behaviour of a binary mixture of twist-bend nematogens. A binary phase diagram for mixtures of imino- linked cyanobiphenyl (CBI) dimer and imino- linked benzoyloxy-benzylidene (BB) dimer shows two distinct domains. While mixtures containing less than 35 mol % of BB possess a wide temperature range twist-bend nematic phase, the mixtures containing 55–80 mol % of BB exhibit a smectic phase despite that both pure compounds display a Iso–N–NTB–Cr phase sequence. The phase diagram shows that the addition of BB of up to 30 mol % significantly extends the temperature range of the NTB phase, maintaining the temperature range of the nematic phase. The periodicity, obtained by atomic force microscopy (AFM) imaging, is in the range of 6– 7 nm. The induction of the smectic phase in the mixtures containing 55–80 mol % of BB was confirmed using polarising optical microscopy (POM), differential scanning calorimetry (DSC) and X-ray diffraction. The origin of the intercalated smectic phase was unravelled by combined spectroscopic and computational methods and can be traced to conformational disorder of the terminal chains. These results show the importance of understanding the phase behaviour of binary mixtures, not only in targeting a wide temperature range but also in controlling the self-organizing processes.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekt / tema
HRZZ-IP-2014-09-1525 - Kiralnost od akiralnih tekućih kristala (Andreja Lesac, )

Ustanove
Institut "Ruđer Bošković", Zagreb

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus


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