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Pregled bibliografske jedinice broj: 933796

A case study of supramolecular organization: One ferrocene substituted iminodiacetamide and its chloroform solvate


Juraj, Natalija P.; Le Pennec, Jeremy; Perić, Berislav; Kirin, Srećko I.
A case study of supramolecular organization: One ferrocene substituted iminodiacetamide and its chloroform solvate // Croatica chemica acta, 90 (2017), 4; 613-623 doi:10.5562/cca3270 (međunarodna recenzija, članak, znanstveni)


Naslov
A case study of supramolecular organization: One ferrocene substituted iminodiacetamide and its chloroform solvate

Autori
Juraj, Natalija P. ; Le Pennec, Jeremy ; Perić, Berislav ; Kirin, Srećko I.

Izvornik
Croatica chemica acta (0011-1643) 90 (2017), 4; 613-623

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
Amides, ferrocene, hydrogen bonding, iminodiacetamide, supramolecular chemistry

Sažetak
This paper describes the synthesis of an amide based conjugate of ferrocene (Fc), ethylenediamine (eda) and iminodiacetamide (imda), Fc-eda-imda (2). The compound (2) is characterized by various spectroscopic, crystallographic and thermoanalytical techniques in solid state and in solution. By crystallization of the title compound 2 from methanol or chloroform, two different crystalline forms 2a and 2b were obtained, respectively. In their X-ray single crystal structures, 2a and 2b reveal similar 2D hydrogen bonding network, but differ by supramolecular organization, namely aromatic π – π stacking interactions in the third spatial dimension.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekt / tema
HRZZ-IP-2014-09-1461 - Minimalni umjetni enzimi: Proširenje primjene posredne indukcije na nove supstrate i nove asimetrične reakcije (Srećko Kirin, )

Ustanove
Institut "Ruđer Bošković", Zagreb

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus


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