Building metal-organic architectures by the design (CROSBI ID 660003)
Prilog sa skupa u zborniku | sažetak izlaganja sa skupa
Podaci o odgovornosti
Đaković, Marijana ; Borovina, Mladen ; Aakeröy ; Kodrin, Ivan
engleski
Building metal-organic architectures by the design
One of the primary challenges of crystal engineering is to deliver solids with a targeted physical property or response. As performance and properties of solid materials can be directly modified by controlling the nature of the 3-D assembly of molecules/ions, the first step towards a targeted property/response requires control over specific structural topologies. Unfortunately, a lack of robust and transferable guidelines for pre-planned synthesis based on non-covalent interactions still stands in the way of predicatable supramolecular assemblies of metal-containing solids. In this contribution we present our attempts and success in controlling the supramolecular assembly of metal-complexes (of various dimensionalities) via fine-tuning the strength of hydrogen- and halogen-bond donors and acceptors. The use of calculated molecular electrostatic potential surfaces for ranking potential donors and acceptors in the system is shown to be a useful method for achieveing the desired supramolecular outcome.
supramolecular architectures ; metal-organic complexes ; MEP ; hydrogen bond
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Podaci o prilogu
37-37.
2018.
objavljeno
Podaci o matičnoj publikaciji
26th Annual Meeting of the German Crystallographic Society (DGK), Book of Abstracts ; dodatak časopisu Zeitschrift für Kristallographie
Podaci o skupu
26th Annual Meeting of the German Crystallographic Society (DGK 2018)
predavanje
05.03.2018-08.03.2018
Essen, Njemačka
Povezanost rada
Kemija