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Probing semiconductivity in crystals of stable semiquinone radicals: organic salts of 5, 6- dichloro-2, 3-dicyanosemiuinone (DDQ) radical anions†


(Hrvatsko-njemačka bilaterala - DAAD) Molčanov, Krešimir; Stalke, Dietmar; Šantić, Ana; Demeshko, Serhiy; Stilinović, Vladimir; Mou, Zhongyu; Kertesz, Miklos; Kojić-Prodić, Biserka
Probing semiconductivity in crystals of stable semiquinone radicals: organic salts of 5, 6- dichloro-2, 3-dicyanosemiuinone (DDQ) radical anions† // Crystengcomm, 20 (2018), 1862-1873 doi:10.1039/c7ce02146a (međunarodna recenzija, članak, znanstveni)


Naslov
Probing semiconductivity in crystals of stable semiquinone radicals: organic salts of 5, 6- dichloro-2, 3-dicyanosemiuinone (DDQ) radical anions†
(Probing semiconductivity in crystals of stable semiquinone radicals: organic salts of 5, 6- dichloro-2, 3-dicyanosemiquinone (DDQ) radical anions)

Autori
Molčanov, Krešimir ; Stalke, Dietmar ; Šantić, Ana ; Demeshko, Serhiy ; Stilinović, Vladimir ; Mou, Zhongyu ; Kertesz, Miklos ; Kojić-Prodić, Biserka

Kolaboracija
Hrvatsko-njemačka bilaterala - DAAD

Izvornik
Crystengcomm (1466-8033) 20 (2018); 1862-1873

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
Semiquinones, pi-stacking, semiconductivity, magnetic properties

Sažetak
The structural parameters and semiconductivity of crystals with stacked 5, 6-dichloro-2, 3-dicyanosemiquinone (DDQ) radicals were studied for a series of the first nine salts of DDQ with substituted N-ethyl- and N-methylpyridinium cations. Structures with stacks of equidistant radicals (interplanar separation <3.3 Å) are fairly good semiconductors (10−9 S cm−1), while those with Peierls-distorted stacks comprising diamagnetic dimers of radicals (interplanar separations are <3.1 Å within the dimers and >3.4 Å between the dimers) are insulators. DFT calculations indicate the covalent character (pancake bonding) of the interactions between the DDQ radical anions. The inductive effects of electronegative substituents (halogeno and cyano) on the quinoid ring stabilise the radicals, but also increase the HOMO–LUMO gap, resulting in lower electrical conductivity.

Izvorni jezik
Hrvatski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekt / tema
HRZZ-IP-2014-09-4079 - Novi metal-organsi sustavi s oksalatnim i kinoidnim ligandima s podešenim svojstvima pogodnim za primjenu (Krešimir Molčanov, )

Ustanove
Institut "Ruđer Bošković", Zagreb

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus


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