engleski

Aromatic C-­Nitroso Compounds and their Dimers: A Model for Physical Organic Chemistry of Reactions in Crystalline Molecular Solids

Dimerization of aromatic C-­nitroso compounds and dissociation of the corresponding azodioxy dimers are represented as a model for studying the thermal organic solid-­state reaction mechanisms. Reactivity of the model molecules in solid state is examined under the different topotactic conditions, especially as a function of disordering, surface defects, and phase transformations. The dependence of the reaction rate on the distance between reacting molecules (topochemical effect) is discussed in more detail. The investigation is also extended to the reactions in the condensed one-­ and two-­dimensional molecular arrangements.

Aromatic C-nitroso compounds ; Dimerization ; Solid-state kinetics

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