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Application of a Numerical Method for the Analysis of Metglas 2826 MB Crystallization Kinetics (CROSBI ID 95897)

Prilog u časopisu | izvorni znanstveni rad | međunarodna recenzija

Kurajica, Stanislav ; Schmauch, Jorg ; Tkalčec, Emilija Application of a Numerical Method for the Analysis of Metglas 2826 MB Crystallization Kinetics // Croatica chemica acta, 75 (2002), 3; 693-699-x

Podaci o odgovornosti

Kurajica, Stanislav ; Schmauch, Jorg ; Tkalčec, Emilija

engleski

Application of a Numerical Method for the Analysis of Metglas 2826 MB Crystallization Kinetics

Crystallization kinetics of &#947 ; -FeNiMo solid solution in Metglas 2826 MB was studied by isothermal differential scanning calorimetry (DSC). The Johnson-Mehl-Avrami (JMA) equation was used to describe crystallization process. In order to calculate kinetic parameters a new model for numerical analysis of isothermally obtained DSC data was successfully applied. For the purposes of method evaluation the classical, analytical method of data analysis was also performed. The apparent activation energies obtained were 280&plusmn ; 22 kJ mol-1 and 296&plusmn ; 23 kJ mol-1 for analytical and numerical method, respectively. The Avrami exponents obtained by the both methods lie between 1.75 and 1.95.

Crystallization kinetics; Differential scanning calorimetry; Johnson-Mehl-Avrami equation; Metglass 2826 MB; Numerical model.

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Podaci o izdanju

75 (3)

2002.

693-699-x

objavljeno

0011-1643

Povezanost rada

Kemijsko inženjerstvo

Indeksiranost