Napredna pretraga

Pregled bibliografske jedinice broj: 891162

Cis- vs. trans- square-planar palladium(II) and platinum(II) complexes with triphenylphosphine amino acid bioconjugates


Kokan, Zoran; Perić, Berislav; Kovačević, Goran; Brozovic, Anamaria; Metzler-Nolte, Nils; Kirin, Srećko I.
Cis- vs. trans- square-planar palladium(II) and platinum(II) complexes with triphenylphosphine amino acid bioconjugates // European journal of inorganic chemistry, 2017 (2017), 33; 3928-3937 doi:10.1002/ejic.201700679 (međunarodna recenzija, članak, znanstveni)


Naslov
Cis- vs. trans- square-planar palladium(II) and platinum(II) complexes with triphenylphosphine amino acid bioconjugates

Autori
Kokan, Zoran ; Perić, Berislav ; Kovačević, Goran ; Brozovic, Anamaria ; Metzler-Nolte, Nils ; Kirin, Srećko I.

Izvornik
European journal of inorganic chemistry (1434-1948) 2017 (2017), 33; 3928-3937

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
Palladium ; Platinum ; Phosphine ligands ; Amino acids ; Biological activity

Sažetak
Triphenylphosphine–amino acid bioconjugates Ph2P-pC6H4-Aa-OR [Lig ; Aa = glycine (1G), alanine (2A), valine (3V), isoleucine (4I), proline (5P), or phenylalanine (6F)] were synthesized and used as monodentate ligands for the preparation of twelve metal complexes, [MCl2(Lig)2] (M = PdII or PtII). All of the prepared compounds were characterized by spectroscopic methods, and the structures of ligand 1G and complexes 1GPd, 4IPd, and 6FPd were determined by X-ray single-crystal diffraction. The cis and trans configurations of the square-planar metal complexes were investigated by solution NMR spectroscopy and computational methods.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekt / tema
HRZZ-IP-2014-09-1461 - Minimalni umjetni enzimi: Proširenje primjene posredne indukcije na nove supstrate i nove asimetrične reakcije (Srećko Kirin, )

Ustanove
Institut "Ruđer Bošković", Zagreb

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • Arts & Humanities Citation Index (A&HCI)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus


Citati