Nalazite se na CroRIS probnoj okolini. Ovdje evidentirani podaci neće biti pohranjeni u Informacijskom sustavu znanosti RH. Ako je ovo greška, CroRIS produkcijskoj okolini moguće je pristupi putem poveznice www.croris.hr
izvor podataka: crosbi

Simulation of square wave voltammetry of three step redox reactions on spherical electrodes (CROSBI ID 240824)

Prilog u časopisu | izvorni znanstveni rad | međunarodna recenzija

Komorsky-Lovrić, Šebojka ; Lovrić, Milivoj Simulation of square wave voltammetry of three step redox reactions on spherical electrodes // Croatica chemica acta, 90 (2017), 1; 27-35. doi: 10.5562/cca3048

Podaci o odgovornosti

Komorsky-Lovrić, Šebojka ; Lovrić, Milivoj

engleski

Simulation of square wave voltammetry of three step redox reactions on spherical electrodes

The theory of three step electrode reaction is developed for square wave voltammetry on stationary spherical electrodes. It was assumed that all electroactive species are solution soluble. The dependence of the response on the thermodynamic stability of intermediates, on the electrode radius and the scan direction is investigated for the fast and reversible electrode reactions. The criterion of reversibility is postulated. Furthermore, the influence of electrode kinetics on the response was calculated for the cathodic and anodic scan directions. The difference in responses caused by the variation of scan direction is an indication of multiple electron transfers. The method for the estimation of transfer coefficient is demonstrated.

square wave voltammetry ; three step electrode reaction ; theory ; spherical electrode ; kinetics of electrode reaction

nije evidentirano

nije evidentirano

nije evidentirano

nije evidentirano

nije evidentirano

nije evidentirano

Podaci o izdanju

90 (1)

2017.

27-35

objavljeno

0011-1643

1334-417X

10.5562/cca3048

Povezanost rada

Kemija

Poveznice
Indeksiranost