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In Situ Monitoring of the Mechanosynthesis of the Archetypal Metal–Organic Framework HKUST-1 : Effect of Liquid Additives on the Milling Reactivity


Stolar, Tomislav; Batzdorf, Lisa; Lukin, Stipe; Žilić, Dijana; Motillo, Cristina; Friščić, Tomislav; Emmerling, Franziska; Halasz, Ivan; Užarević, Krunoslav
In Situ Monitoring of the Mechanosynthesis of the Archetypal Metal–Organic Framework HKUST-1 : Effect of Liquid Additives on the Milling Reactivity // Inorganic chemistry, 56 (2017), 11; 6599-6608 doi:10.1021/acs.inorgchem.7b00707 (međunarodna recenzija, članak, znanstveni)


Naslov
In Situ Monitoring of the Mechanosynthesis of the Archetypal Metal–Organic Framework HKUST-1 : Effect of Liquid Additives on the Milling Reactivity

Autori
Stolar, Tomislav ; Batzdorf, Lisa ; Lukin, Stipe ; Žilić, Dijana ; Motillo, Cristina ; Friščić, Tomislav ; Emmerling, Franziska ; Halasz, Ivan ; Užarević, Krunoslav

Izvornik
Inorganic chemistry (0020-1669) 56 (2017), 11; 6599-6608

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
Mechanochemistry ; metal-organic frameworks ; HKUST-1 ; in situ X-ray diffraction ; ESR ; intermediate ; coordination polymers

Sažetak
We have applied in situ monitoring of mechanochemical reactions by high-energy synchrotron powder X-ray diffraction to study the role of liquid additives on the mechanochemical synthesis of the archetypal metal–organic framework (MOF) HKUST-1, which was one of the first and is still among the most widely investigated MOF materials to be synthesized by solvent-free procedures. It is shown here how the kinetics and mechanisms of the mechanochemical synthesis of HKUST-1 can be influenced by milling conditions and additives, yielding on occasion two new and previously undetected intermediate phases containing a mononuclear copper core, and that finally rearrange to form the HKUST-1 architecture. On the basis of in situ data, we were able to tune and direct the milling reactions toward the formation of these intermediates, which were isolated and characterized by spectroscopic and structural means and their magnetic properties compared to those of HKUST-1. The results have shown that despite the relatively large breadth of analysis available for such widely investigated materials as HKUST-1, in situ monitoring of milling reactions can help in the detection and isolation of new materials and to establish efficient reaction conditions for the mechanochemical synthesis of porous MOFs.

Izvorni jezik
Engleski

Znanstvena područja
Fizika, Kemija



POVEZANOST RADA


Projekt / tema
HRZZ-IP-2013-11-1108 - Karakterizacija niskotemperaturne molekulske dinamike sustava s neuređenom rešetkom metodom ESR (Marina Kveder, )
HRZZ-UIP-2014-09-4744 - Mehaniokemijska reaktivnost pod kontroliranim uvjetima temperature i atmosfere za čišću sintezu funkcionalnih materijala (Krunoslav Užarević, )

Ustanove
Institut "Ruđer Bošković", Zagreb

Citiraj ovu publikaciju

Stolar, Tomislav; Batzdorf, Lisa; Lukin, Stipe; Žilić, Dijana; Motillo, Cristina; Friščić, Tomislav; Emmerling, Franziska; Halasz, Ivan; Užarević, Krunoslav
In Situ Monitoring of the Mechanosynthesis of the Archetypal Metal–Organic Framework HKUST-1 : Effect of Liquid Additives on the Milling Reactivity // Inorganic chemistry, 56 (2017), 11; 6599-6608 doi:10.1021/acs.inorgchem.7b00707 (međunarodna recenzija, članak, znanstveni)
Stolar, T., Batzdorf, L., Lukin, S., Žilić, D., Motillo, C., Friščić, T., Emmerling, F., Halasz, I. & Užarević, K. (2017) In Situ Monitoring of the Mechanosynthesis of the Archetypal Metal–Organic Framework HKUST-1 : Effect of Liquid Additives on the Milling Reactivity. Inorganic chemistry, 56 (11), 6599-6608 doi:10.1021/acs.inorgchem.7b00707.
@article{article, year = {2017}, pages = {6599-6608}, DOI = {10.1021/acs.inorgchem.7b00707}, keywords = {mechanochemistry, metal-organic frameworks, HKUST-1, in situ X-ray diffraction, ESR, intermediate, coordination polymers}, journal = {Inorganic chemistry}, doi = {10.1021/acs.inorgchem.7b00707}, volume = {56}, number = {11}, issn = {0020-1669}, title = {In Situ Monitoring of the Mechanosynthesis of the Archetypal Metal–Organic Framework HKUST-1 : Effect of Liquid Additives on the Milling Reactivity}, keyword = {mechanochemistry, metal-organic frameworks, HKUST-1, in situ X-ray diffraction, ESR, intermediate, coordination polymers} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus
  • MEDLINE


Uključenost u ostale bibliografske baze podataka:


  • Computer and Information Systems Abstracts
  • British Library
  • CAS
  • EBSCOhost
  • Proquest
  • Thomson-Gale
  • SwetsWise


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