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Pregled bibliografske jedinice broj: 884124

Mechanistic study of mechanochemical Knoevenagel reaction


Tireli, Martina; Lukin, Stipe; di Michael, Marco; Halasz, Ivan; Užarević, Krunoslav
Mechanistic study of mechanochemical Knoevenagel reaction // Book of Abstracts / Juribašić Kulcsar, Marina ; Halasz, Ivan (ur.).
Zagreb: Ruđer Bošković Institute, 2017. str. 83-83 (poster, nije recenziran, sažetak, ostalo)


CROSBI ID: 884124 Za ispravke kontaktirajte CROSBI podršku putem web obrasca

Naslov
Mechanistic study of mechanochemical Knoevenagel reaction
(Mechanhanistic study of mechanochemical Knoevenagel reaction)

Autori
Tireli, Martina ; Lukin, Stipe ; di Michael, Marco ; Halasz, Ivan ; Užarević, Krunoslav

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, ostalo

Izvornik
Book of Abstracts / Juribašić Kulcsar, Marina ; Halasz, Ivan - Zagreb : Ruđer Bošković Institute, 2017, 83-83

ISBN
978-953-7941-15-4

Skup
Solid-State Science & Research

Mjesto i datum
Zagreb, Hrvatska, 28-30.06.2017

Vrsta sudjelovanja
Poster

Vrsta recenzije
Nije recenziran

Ključne riječi
mechanistic study, mechanochemistry, organic reactions, Knoevenagel reaction, in situ Raman, Raman spectroscopy, synchrotron XRD

Sažetak
Organic synthesis is widely used in pharmaceutical and chemical industry, but the need for cleaner and safer synthesis was the key for success of solid state reactions.[1] Mechanochemical organic reaction are carried out without the need for solvents, conventional catalysts, in shorter reaction time and with higher product yield.[2] Development of in situ methods in real time which permit reaction monitoring was extremely important for further development of mechanochemical methods and investigation of mechanistic studies. The Knoevenagel condensation is a nuchleophilic addition reaction of an active hydrogen compound to a carbonyl group and it is used for forming a new C-C bond.[3] Here we present simultaneous synchrotron powder X-ray diffraction and Raman for in situ monitoring of mechanochemical Knoevenagel reactions between aromatic aldehyde 1-4 and barbituric acid. In situ monitoring enabled us direct insight into the fundamental aspects of solid-state Knoevenagel reactions and enabled us optimization of this important class of organic reactions.

Izvorni jezik
Engleski

Znanstvena područja
Kemija, Farmacija



POVEZANOST RADA


Projekti:
HRZZ-UIP-2014-09-4744 - Mehanokemijska reaktivnost pod kontroliranim uvjetima temperature i atmosfere za čišću sintezu funkcionalnih materijala (MECHANOCONTROL) (Užarević, Krunoslav, HRZZ - 2014-09) ( POIROT)

Ustanove:
Institut "Ruđer Bošković", Zagreb

Profili:

Avatar Url Ivan Halasz (autor)

Avatar Url Martina Tireli (autor)

Avatar Url Stipe Lukin (autor)

Avatar Url Krunoslav Užarević (autor)


Citiraj ovu publikaciju

Tireli, Martina; Lukin, Stipe; di Michael, Marco; Halasz, Ivan; Užarević, Krunoslav
Mechanistic study of mechanochemical Knoevenagel reaction // Book of Abstracts / Juribašić Kulcsar, Marina ; Halasz, Ivan (ur.).
Zagreb: Ruđer Bošković Institute, 2017. str. 83-83 (poster, nije recenziran, sažetak, ostalo)
Tireli, M., Lukin, S., di Michael, M., Halasz, I. & Užarević, K. (2017) Mechanistic study of mechanochemical Knoevenagel reaction. U: Juribašić Kulcsar, M. & Halasz, I. (ur.)Book of Abstracts.
@article{article, year = {2017}, pages = {83-83}, keywords = {mechanistic study, mechanochemistry, organic reactions, Knoevenagel reaction, in situ Raman, Raman spectroscopy, synchrotron XRD}, isbn = {978-953-7941-15-4}, title = {Mechanistic study of mechanochemical Knoevenagel reaction}, keyword = {mechanistic study, mechanochemistry, organic reactions, Knoevenagel reaction, in situ Raman, Raman spectroscopy, synchrotron XRD}, publisher = {Ru\djer Bo\v{s}kovi\'{c} Institute}, publisherplace = {Zagreb, Hrvatska} }
@article{article, year = {2017}, pages = {83-83}, keywords = {mechanistic study, mechanochemistry, organic reactions, Knoevenagel reaction, in situ Raman, Raman spectroscopy, synchrotron XRD}, isbn = {978-953-7941-15-4}, title = {Mechanhanistic study of mechanochemical Knoevenagel reaction}, keyword = {mechanistic study, mechanochemistry, organic reactions, Knoevenagel reaction, in situ Raman, Raman spectroscopy, synchrotron XRD}, publisher = {Ru\djer Bo\v{s}kovi\'{c} Institute}, publisherplace = {Zagreb, Hrvatska} }




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