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Pregled bibliografske jedinice broj: 884124

Mechanistic study of mechanochemical Knoevenagel reaction


Tireli, Martina; Lukin, Stipe; di Michael, Marco; Halasz, Ivan; Užarević, Krunoslav
Mechanistic study of mechanochemical Knoevenagel reaction // Solid-State Science & Research : book of abstracts and programme / Juribašić Kulcsar, Marina ; Halasz, Ivan (ur.).
Zagreb: Ruđer Bošković Institute, 2017. str. 83-83 (poster, nije recenziran, sažetak, znanstveni)


CROSBI ID: 884124 Za ispravke kontaktirajte CROSBI podršku putem web obrasca

Naslov
Mechanistic study of mechanochemical Knoevenagel reaction
(Mechanhanistic study of mechanochemical Knoevenagel reaction)

Autori
Tireli, Martina ; Lukin, Stipe ; di Michael, Marco ; Halasz, Ivan ; Užarević, Krunoslav

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
Solid-State Science & Research : book of abstracts and programme / Juribašić Kulcsar, Marina ; Halasz, Ivan - Zagreb : Ruđer Bošković Institute, 2017, 83-83

ISBN
978-953-7941-15-4

Skup
Solid-State Science & Research

Mjesto i datum
Zagreb, Hrvatska, 28-30.06.2017

Vrsta sudjelovanja
Poster

Vrsta recenzije
Nije recenziran

Ključne riječi
mechanistic study ; mechanochemistry ; organic reactions, Knoevenagel reaction ; in situ Raman ; Raman spectroscopy ; synchrotron XRD

Sažetak
Organic synthesis is widely used in pharmaceutical and chemical industry, but the need for cleaner and safer synthesis was the key for success of solid state reactions.[1] Mechanochemical organic reaction are carried out without the need for solvents, conventional catalysts, in shorter reaction time and with higher product yield.[2] Development of in situ methods in real time which permit reaction monitoring was extremely important for further development of mechanochemical methods and investigation of mechanistic studies. The Knoevenagel condensation is a nuchleophilic addition reaction of an active hydrogen compound to a carbonyl group and it is used for forming a new C-C bond.[3] Here we present simultaneous synchrotron powder X-ray diffraction and Raman for in situ monitoring of mechanochemical Knoevenagel reactions between aromatic aldehyde 1-4 and barbituric acid. In situ monitoring enabled us direct insight into the fundamental aspects of solid-state Knoevenagel reactions and enabled us optimization of this important class of organic reactions.

Izvorni jezik
Engleski

Znanstvena područja
Kemija, Farmacija



POVEZANOST RADA


Projekti:
HRZZ-UIP-2014-09-4744 - Mehanokemijska reaktivnost pod kontroliranim uvjetima temperature i atmosfere za čišću sintezu funkcionalnih materijala (MECHANOCONTROL) (Užarević, Krunoslav, HRZZ - 2014-09) ( POIROT)

Ustanove:
Institut "Ruđer Bošković", Zagreb

Profili:

Avatar Url Ivan Halasz (autor)

Avatar Url Martina Tireli (autor)

Avatar Url Stipe Lukin (autor)

Avatar Url Krunoslav Užarević (autor)


Citiraj ovu publikaciju:

Tireli, Martina; Lukin, Stipe; di Michael, Marco; Halasz, Ivan; Užarević, Krunoslav
Mechanistic study of mechanochemical Knoevenagel reaction // Solid-State Science & Research : book of abstracts and programme / Juribašić Kulcsar, Marina ; Halasz, Ivan (ur.).
Zagreb: Ruđer Bošković Institute, 2017. str. 83-83 (poster, nije recenziran, sažetak, znanstveni)
Tireli, M., Lukin, S., di Michael, M., Halasz, I. & Užarević, K. (2017) Mechanistic study of mechanochemical Knoevenagel reaction. U: Juribašić Kulcsar, M. & Halasz, I. (ur.)Solid-State Science & Research : book of abstracts and programme.
@article{article, author = {Tireli, Martina and Lukin, Stipe and di Michael, Marco and Halasz, Ivan and U\v{z}arevi\'{c}, Krunoslav}, year = {2017}, pages = {83-83}, keywords = {mechanistic study, mechanochemistry, organic reactions, Knoevenagel reaction, in situ Raman, Raman spectroscopy, synchrotron XRD}, isbn = {978-953-7941-15-4}, title = {Mechanistic study of mechanochemical Knoevenagel reaction}, keyword = {mechanistic study, mechanochemistry, organic reactions, Knoevenagel reaction, in situ Raman, Raman spectroscopy, synchrotron XRD}, publisher = {Ru\djer Bo\v{s}kovi\'{c} Institute}, publisherplace = {Zagreb, Hrvatska} }
@article{article, author = {Tireli, Martina and Lukin, Stipe and di Michael, Marco and Halasz, Ivan and U\v{z}arevi\'{c}, Krunoslav}, year = {2017}, pages = {83-83}, keywords = {mechanistic study, mechanochemistry, organic reactions, Knoevenagel reaction, in situ Raman, Raman spectroscopy, synchrotron XRD}, isbn = {978-953-7941-15-4}, title = {Mechanhanistic study of mechanochemical Knoevenagel reaction}, keyword = {mechanistic study, mechanochemistry, organic reactions, Knoevenagel reaction, in situ Raman, Raman spectroscopy, synchrotron XRD}, publisher = {Ru\djer Bo\v{s}kovi\'{c} Institute}, publisherplace = {Zagreb, Hrvatska} }




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