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Pregled bibliografske jedinice broj: 881361

A comparative study of toluene oxidation on different metal oxides


Duplančić, Marina; Tomašić, Vesna; Kurajica, Stanislav; Minga, Iva; Maduna Valkaj, Karolina
A comparative study of toluene oxidation on different metal oxides // Chemical Engineering Transactions, 57 (2017), 889-894 doi:10.3303/CET1757149 (podatak o recenziji nije dostupan, članak, znanstveni)


CROSBI ID: 881361 Za ispravke kontaktirajte CROSBI podršku putem web obrasca

Naslov
A comparative study of toluene oxidation on different metal oxides

Autori
Duplančić, Marina ; Tomašić, Vesna ; Kurajica, Stanislav ; Minga, Iva ; Maduna Valkaj, Karolina

Izvornik
Chemical Engineering Transactions (2283-9216) 57 (2017); 889-894

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
toluene oxidation ; metal oxide based catalysts

Sažetak
This work reports the results of experimental and theoretical investigation of toluene oxidation on different metal oxide based catalysts (manganese oxide, MnOx, mixed manganese-iron oxide, MnFe, perovskite-type manganese oxide, LaMnO3 and commercial Pt-Al2O3 catalyst). Particular attention was devoted to single and mixed manganese based oxides and ceria based materials as alternatives to conventionally used noble metal containing catalysts. Toluene oxidation was performed under steady- state conditions in an integral fixed bed reactor operating over a wider range of reaction temperatures and at various space times. The influence of reaction variables on the rate of toluene oxidation was examined using the simple first-order kinetic model and the one-dimensional (1D) pseudo-homogeneous model to describe the reaction system. The proposed model was verified comparing the theoretical predictions with the experimental laboratory results. The results of catalytic tests indicated that the mixed manganese-iron oxide (MnFe) exhibited remarkable catalytic activity for the toluene oxidation, almost comparable with the activity of the commercial Pt-Al2O3. The reaction temperature T50 corresponding to 50% of the toluene conversion was observed at 419 K for the MnFe oxide and at 405 K for the Pt-Al2O3. A very good agreement of experimental data with the proposed 1D model was obtained. Based on the shape of the light- off curve and the values of the apparent activation energies, which decreased from 120.36 kJ/mol to 16.88 kJ/mol with reaction temperature increase, it was concluded that the reaction rate was probably limited by the mass transfer, no matter the relatively small catalyst particle size fraction employed in this study (315 - 400μm).

Izvorni jezik
Engleski

Znanstvena područja
Kemijsko inženjerstvo, Interdisciplinarne tehničke znanosti



POVEZANOST RADA


Ustanove:
Fakultet kemijskog inženjerstva i tehnologije, Zagreb

Poveznice na cjeloviti tekst rada:

doi

Citiraj ovu publikaciju:

Duplančić, Marina; Tomašić, Vesna; Kurajica, Stanislav; Minga, Iva; Maduna Valkaj, Karolina
A comparative study of toluene oxidation on different metal oxides // Chemical Engineering Transactions, 57 (2017), 889-894 doi:10.3303/CET1757149 (podatak o recenziji nije dostupan, članak, znanstveni)
Duplančić, M., Tomašić, V., Kurajica, S., Minga, I. & Maduna Valkaj, K. (2017) A comparative study of toluene oxidation on different metal oxides. Chemical Engineering Transactions, 57, 889-894 doi:10.3303/CET1757149.
@article{article, year = {2017}, pages = {889-894}, DOI = {10.3303/CET1757149}, keywords = {toluene oxidation, metal oxide based catalysts}, journal = {Chemical Engineering Transactions}, doi = {10.3303/CET1757149}, volume = {57}, issn = {2283-9216}, title = {A comparative study of toluene oxidation on different metal oxides}, keyword = {toluene oxidation, metal oxide based catalysts} }
@article{article, year = {2017}, pages = {889-894}, DOI = {10.3303/CET1757149}, keywords = {toluene oxidation, metal oxide based catalysts}, journal = {Chemical Engineering Transactions}, doi = {10.3303/CET1757149}, volume = {57}, issn = {2283-9216}, title = {A comparative study of toluene oxidation on different metal oxides}, keyword = {toluene oxidation, metal oxide based catalysts} }

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