engleski

On the zinc(II) and mercury(II) compounds with Schiff-base N-(p-anisoyl)-2-oxo-1- naphthylideneamine. Tautomerism of the ligand and polymerization of mercury compound via Hg⋯I contact

The 1:2 zinc(II) halide complexes of general formula [ZnX2(LH)2] and the 1:1 mercury(II) halide complexes of general formula [HgX2(LH)] with N-(p- anisoyl)-2-oxo-1-naphthylideneamine (LH) are prepared and characterized. IR- spectrometry study as well as the crystal structures of two of them reveal monodentate (via oxygen) ligation of the neutral Schiff- base, while UV–Vis as well as H-1 and C-13 NMR spectra suggest that the dissolving of the complexes is followed by the decomposition into the parent molecules.

Adducts ; Schiff-bases ; Crystal structures ; IR- ; UV- ; NMR-spectrometry ; Thermal analysis

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