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Supramolecular assemblies of Cu(II) and Cu(I) pyrazine based complexes: different or alike?

In our attempts to give some guidelines for reliable synthetic routes of supramolecular assemblies of metal-containing materials we have firstly focused on recognition and binding of various functionalities in the presence of (potentially) disruptive halide ions. Therefore, we synthesized a series of halide complexes of copper(I) and copper(II) with 2-halopyrazines.

crystal engineering; copper complexes; halopyrazines; crystal structure

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