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Pregled bibliografske jedinice broj: 838188

Defying Stereotypes with Nanodiamonds: Stable Primary Diamondoid Phosphines


Moncea, Oana; Gunawan, Maria A.; Poinsot, Didier; Cattey, Hélène; Becker, Jonathan; Yurchenko, Raisa I.; Butova, Ekaterina D.; Hausmann, Heike; Šekutor, Marina; Fokin, Andrey A. et al.
Defying Stereotypes with Nanodiamonds: Stable Primary Diamondoid Phosphines // Journal of organic chemistry, 81 (2016), 19; 8759-8769 doi:10.1021/acs.joc.6b01219 (međunarodna recenzija, članak, znanstveni)


Naslov
Defying Stereotypes with Nanodiamonds: Stable Primary Diamondoid Phosphines

Autori
Moncea, Oana ; Gunawan, Maria A. ; Poinsot, Didier ; Cattey, Hélène ; Becker, Jonathan ; Yurchenko, Raisa I. ; Butova, Ekaterina D. ; Hausmann, Heike ; Šekutor, Marina ; Fokin, Andrey A. ; Hierso, Jean-Cyrille ; Schreiner, Peter R.

Izvornik
Journal of organic chemistry (0022-3263) 81 (2016), 19; 8759-8769

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
Nanodiamonds ; Diamondoid Phosphines ; diamantane ; adamantane ; adamantylphosphine

Sažetak
Direct unequal C−H bond difunctionalization of phosphorylated diamantane was achieved in high yield from the corresponding phosphonates. Reduction of the functionalized phosphonates provides access to novel primary and secondary alkyl/aryl diamantane phosphines. The prepared primary diamantyl phosphines are quite air stable compared to their adamantyl and especially alkyl or aryl analogues. This finding is corroborated by comparing the singly occupied molecular orbital energy levels of the corresponding phosphine radical cations obtained by density functional theory computations.

Izvorni jezik
Engleski

Znanstvena područja
Kemija

Napomena
M.Š. would like to thank the Alexander-von-Humboldt Foundation for a Humboldt Research Fellowship for Postdoctoral Researchers.



POVEZANOST RADA


Autor s matičnim brojem:
Marina Šekutor, (312901)

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • Arts & Humanities Citation Index (A&HCI)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus


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