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Vapour-induced solid-state C–H bond activation for the clean synthesis of an organopalladium biothiol sensor


Monas, Andrea; Užarević, Krunoslav; Halasz, Ivan; Juribašić Kulcsar, Marina; Ćurić, Manda
Vapour-induced solid-state C–H bond activation for the clean synthesis of an organopalladium biothiol sensor // Chemical communications, 52 (2016), 88; 12960-12963 doi:10.1039/c6cc06062e (međunarodna recenzija, članak, znanstveni)


Naslov
Vapour-induced solid-state C–H bond activation for the clean synthesis of an organopalladium biothiol sensor

Autori
Monas, Andrea ; Užarević, Krunoslav ; Halasz, Ivan ; Juribašić Kulcsar, Marina ; Ćurić, Manda

Izvornik
Chemical communications (1359-7345) 52 (2016), 88; 12960-12963

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
C-H activation ; accelerated aging ; palladium ; azobenzene ; biothiol sensor

Sažetak
Room-temperature accelerated aging in the solid state has been applied for atom- and energy-efficient activation of either one or two C–H bonds of azobenzene and methyl orange by palladium(II) acetate. Organopalladium complexes are prepared in quantitative reactions without potentially harmful side products. Dicyclopalladated methyl orange is water-soluble and is a selective chromogenic biothiol sensor at physiologically-relevant micromolar concentrations in buffered aqueous media.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekt / tema
HRZZ-IP-2014-09-7984 - Zelena sinteza organopaladijevih foto-osjetljivih spojeva
HRZZ-UIP-2014-09-4744 - Mehaniokemijska reaktivnost pod kontroliranim uvjetima temperature i atmosfere za čišću sintezu funkcionalnih materijala (Krunoslav Užarević, )

Ustanove
Institut "Ruđer Bošković", Zagreb

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • Arts & Humanities Citation Index (A&HCI)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus
  • MEDLINE


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