Simulation of differential pulse polarography of irreversible EC mechanism (CROSBI ID 231294)
Prilog u časopisu | izvorni znanstveni rad | međunarodna recenzija
Podaci o odgovornosti
Lovrić, Milivoj
engleski
Simulation of differential pulse polarography of irreversible EC mechanism
A reversible electrode reaction that is followed by totally irreversible chemical reaction is investigated theoretically. The influence of chemical reaction on two components of the net response of differential pulse polarogram is analyzed. It is demonstrated that this EC mechanism depends on two kinetic parameters and that their critical values can be used for the measurement of the rate constant of chemical reaction.
Differential pulse polarography ; EC mechanism ; kinetic measurement ; rate constant
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Podaci o izdanju
52 (10)
2016.
938-942
objavljeno
1023-1935
1608-3342
10.1134/S1023193516100086