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Pregled bibliografske jedinice broj: 830915

Influence of the phthalimide substituents on the photochemical reactivity in photodecarboxylation


Mandić, Leo; Mlinarić-Majerski, Kata; Basarić, Nikola
Influence of the phthalimide substituents on the photochemical reactivity in photodecarboxylation // 5th HRSMC Photochemistry School "Photochemistry, Fundamentals and Applications"
Maastricht, Nizozemska, 2016. (poster, međunarodna recenzija, sažetak, znanstveni)


Naslov
Influence of the phthalimide substituents on the photochemical reactivity in photodecarboxylation

Autori
Mandić, Leo ; Mlinarić-Majerski, Kata ; Basarić, Nikola

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
5th HRSMC Photochemistry School "Photochemistry, Fundamentals and Applications" / - Maastricht, Nizozemska, 2016

Skup
5th HRSMC Photochemistry School "Photochemistry, Fundamentals and Applications"

Mjesto i datum
Maastricht, Nizozemska, 27-31.08.2016

Vrsta sudjelovanja
Poster

Vrsta recenzije
Međunarodna recenzija

Ključne riječi
Photochemistry ; photodecarboxylation ; phthalimide

Sažetak
Photodecarboxylation has been intensively studied due to synthetic applications [1]. Moreover, phototoxicity of some nonsteroidal non-inflammatory drugs is a consequence of photodecarboxylation [2]. Photodecarboxylation can also be initiated by phthalimide in the triplet excited state in a role of an oxidizing agent in photoinduced electron transfer (PET) [3]. Photodecarboxylation study of compound 1a [4] and its isomers (2-5) [5] prompted us to synthesize new derivatives 1b-1g with different substituent at the position 4 of the phthalimide chromophore, and investigate their influence on the photochemical reactivity.

Izvorni jezik
Engleski



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Projekt / tema
HRZZ-IP-2014-09-6312 - Supramolekulska kontrola fotokemijskih reakcija eliminacije (Nikola Basarić, )