Influence of the phthalimide substituents on the photochemical reactivity in photodecarboxylation (CROSBI ID 638525)
Prilog sa skupa u zborniku | sažetak izlaganja sa skupa | međunarodna recenzija
Podaci o odgovornosti
Mandić, Leo ; Mlinarić-Majerski, Kata ; Basarić, Nikola
engleski
Influence of the phthalimide substituents on the photochemical reactivity in photodecarboxylation
Photodecarboxylation has been intensively studied due to synthetic applications [1]. Moreover, phototoxicity of some nonsteroidal non-inflammatory drugs is a consequence of photodecarboxylation [2]. Photodecarboxylation can also be initiated by phthalimide in the triplet excited state in a role of an oxidizing agent in photoinduced electron transfer (PET) [3]. Photodecarboxylation study of compound 1a [4] and its isomers (2-5) [5] prompted us to synthesize new derivatives 1b-1g with different substituent at the position 4 of the phthalimide chromophore, and investigate their influence on the photochemical reactivity.
photochemistry ; photodecarboxylation ; phthalimide
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Podaci o prilogu
2016.
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objavljeno
Podaci o matičnoj publikaciji
5th HRSMC Photochemistry School "Photochemistry, Fundamentals and Applications"
Maastricht:
Podaci o skupu
5th HRSMC Photochemistry School "Photochemistry, Fundamentals and Applications"
poster
27.08.2016-31.08.2016
Maastricht, Nizozemska