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Pregled bibliografske jedinice broj: 82554

Lipophilic derivative of rhodamine 19: characterization and spectroscopic properties


Miljanić, Snežana; Cimerman, Zvjezdana; Frkanec, Leo; Žinić, Mladen
Lipophilic derivative of rhodamine 19: characterization and spectroscopic properties // Analytica Chimica Acta, 468 (2002), 1; 13-25 (međunarodna recenzija, članak, znanstveni)


Naslov
Lipophilic derivative of rhodamine 19: characterization and spectroscopic properties

Autori
Miljanić, Snežana ; Cimerman, Zvjezdana ; Frkanec, Leo ; Žinić, Mladen

Izvornik
Analytica Chimica Acta (0003-2670) 468 (2002), 1; 13-25

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
Rhodamine 19 octadecylamide; Cationic form; Neutral form; Dimer; Fluorescence

Sažetak
A new octadecylamide derivative of rhodamine 19 was synthesized by reaction of rhodamine 19 ethyl ester (rhodamine 6 G) with octadecylamine. This lipophilic dye exists in two forms: as a cationic species containing a secondary amide group and as an electrically neutral molecule containing an additional ring closed between the oxygen of the amide group and the central carbon of the xanthene part. Both forms were isolated and characterized in detail by means of elemental analysis, mass spectrometry, IR, NMR and UV-VIS spectroscopy. Depending on the hydrogen ion activity in solution and the availability of solvent hydrogen for hydrogen bond formation, the cationic form easily converted into a neutral one and vice versa. On the basis of absorption and emission UV-VIS spectroscopic data, the equilibrium of the two forms was studied in various solvents. An increase in dye concentration in acidified methanol/water mixture (volume fraction of water, phi = 80%) led to aggregation of the cationic molecules. Using the UV-VIS absorption data, a corresponding dimerization constant was evaluated.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekt / tema
0098053
119410

Ustanove
Institut "Ruđer Bošković", Zagreb,
Prirodoslovno-matematički fakultet, Zagreb

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus