Functionalised Rigid Rods - Dream or Reality (CROSBI ID 752685)
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Podaci o odgovornosti
Margetić, Davor ; Johnston, Martin R. ; Warrener, Ronald N.
engleski
Functionalised Rigid Rods - Dream or Reality
Approaches to the synthesise of rigid molecular rods containing syn-facially positioned 7-oxa functionality the building BLOCK 12 was identified by molecular modelling as a suitable starting substrate. However, once synthesised, 12 was found to be unstable under the reaction conditions used in an attempt to create rigid rods. This included such coupling protocols as the epoxide based ACE reaction as well as the s-tetrazine system. The foundations have now been laid for future incorporation of 12 into rigid rods.
norbornenes; cycloadditions; molecular modelling
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Podaci o izdanju
Third International Electronic Conference on Synthetic Organic Chemistry (ECSOC-3), http://www.reprints.net/ecsoc-3.htm, September 1-30, 1999, Editors: Esteban Pombo-Villar, Reinhard Neier and Shu-Kun Lin, CD-ROM edition ISBN 3-906980-04-9 Published in
1999.
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