A 1,3-Dipolar Cycloaddition Route to 7-Azanorbornanes: Application to the Synthesis od syn-Facial N-Bridged Polynorbornanes (CROSBI ID 94539)
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Podaci o odgovornosti
Butler, Douglas, N. ; Malpass, John, R. ; Margetić, Davor ; Russell, Richard, A. ; Sun, Guangxing ; Warrener, Ronald, N.
engleski
A 1,3-Dipolar Cycloaddition Route to 7-Azanorbornanes: Application to the Synthesis od syn-Facial N-Bridged Polynorbornanes
Aziridinocyclobutenes react with electron-deficient or ring-strained alkenes to produce 7-azanorbornenes in a novel 1, 3-dipolar cycloaddition reaction suitable for BLOCK assembly protocols.Benzo-7-azanorbornadiene and 7-heterobridged analogues react stereoselectively to produce compounds with syn-facial orientation of their bridges.
dipolar cycloaddition ; azanorbornenes ; synthesis
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