Pregled bibliografske jedinice broj: 815155
UV photoelectron spectroscopy and outer valence electronic structure of dihalobenzenes
UV photoelectron spectroscopy and outer valence electronic structure of dihalobenzenes // Croatica chemica acta, 87 (2014), 4; 495-499 doi:10.5562/cca2438 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 815155 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
UV photoelectron spectroscopy and outer valence electronic structure of dihalobenzenes
Autori
Novak, Igor ; Klasinc, Leo ; Šket, Boris ; Chong, Delano P. ; McGlynn, Sean P.
Izvornik
Croatica chemica acta (0011-1643) 87
(2014), 4;
495-499
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
halobenzenes; inductive effect; resonance effect
Sažetak
The electronic structures of nine dihalobenzenes (C6H4FX ; X = Cl, Br, I) have been studied by UV photoelectron spectroscopy (UPS) and assigned by comparison with the reported spectra of monoha-lobenzenes (C6H5X ; X = Cl, Br, I). and quantum chemical calculations. Our results show that the fluorine substituent modifies energies of π- and halogen lone pair orbitals to a significant degree depending on its location (topology). We also demonstrate that the inductive effect of fluorine atom on the benzene ring can be readily observed and interpreted.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Ustanove:
Institut "Ruđer Bošković", Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
