In situ monitoring and mechanism of the mechanochemical formation of a microporous MOF-74 framework (CROSBI ID 225326)
Prilog u časopisu | izvorni znanstveni rad | međunarodna recenzija
Podaci o odgovornosti
Julien, Patrick A. ; Užarević, Krunoslav ; Katsenis, Athanassios D. ; Kimber, Simon A.J. ; Wang, Timothy ; Farha, Omar K. ; Zhang, Yuancheng ; Casaban, José ; Germann, Luzia ; Etter, Martin ; Dinnebier, Robert E. ; James, Stuart L. ; Halasz, Ivan ; Friščić, Tomislav
engleski
In situ monitoring and mechanism of the mechanochemical formation of a microporous MOF-74 framework
Mechanochemistry provides a rapid, efficient route to metal-organic framework Zn-MOF-74 directly from a metal oxide and without bulk solvent. In situ synchrotron X-ray diffraction monitoring of the reaction course reveals two new phases and an unusual step-wise process in which a close-packed intermediate reacts to form the open framework. The reaction can be performed on a gram scale to yield a highly porous material after activation.
mechanochemistry ; in situ monitoring ; X-ray diffraction ; mechanism ; MOF-74 ; metal-organic framework
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Podaci o izdanju
138 (9)
2016.
2929-2932
objavljeno
0002-7863
10.1021/jacs.5b13038
Povezanost rada
Kemija