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Structure and Morphology of Silica-Reinforced Polypropylene Composites modified with m-EPR Copolymers


Pustak, Anđela; Denac, Matjaž; Leskovac, Mirela; Švab, Iztok; Musil, Vojko; Šmit, Ivan
Structure and Morphology of Silica-Reinforced Polypropylene Composites modified with m-EPR Copolymers // Journal of polymer research, 23 (2016), 37-1 doi:10.1007/s10965-016-0927-3 (međunarodna recenzija, članak, znanstveni)


Naslov
Structure and Morphology of Silica-Reinforced Polypropylene Composites modified with m-EPR Copolymers

Autori
Pustak, Anđela ; Denac, Matjaž ; Leskovac, Mirela ; Švab, Iztok ; Musil, Vojko ; Šmit, Ivan

Izvornik
Journal of polymer research (1022-9760) 23 (2016); 37-1

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
Polypropylene composites; Morphology; Interfacial properties; Structure-property relationship

Sažetak
The effects of different silica (SiO2) types and different contents of two metallocene propylene-based m-EPR elastomers (differing in molecular weight and viscosity) on interfacial properties, structure and morphology of isotactic polypropylene/SiO2/m-EPR composites were investigated. Four silica fillers differing in size (nano- vs. micro-) and surface properties (hydrophilic vs. hydrophobic i.e. polar vs. non-polar) were chosen and added in 4 vol% to isotactic polypropylene. The m-EPR elastomers were added to iPP/SiO2 96/4 composites as possible impact modifier and compatibilizer at the same time in 5, 10, 15, and 20 vol% per 100 vol% of composites (phr). The investigation confirmed the overall prevailing of separated morphology of ternary iPP/SiO2/m-EPR composites, i.e. selectivity of dispersed m-EPR and silica particles toward iPP matrix as was predicted on the basis of adhesion properties. The increase of crystallinity degree and spherulite size with addition of m-EPR elastomers indicated significant solidification effect of added elastomers in addition to opposite nucleation effect of silica particles owing to surface character of filler. The effects of different silica fillers and different contents of two m-EPR elastomers were discussed within the context of morphology/structure-adhesion property relationships of the iPP/SiO2/m-EPR composites.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekt / tema
098-0982904-2955 - Odnosi struktura-svojstvo modificiranih polimernih materijala (Irina Pucić, )

Ustanove
Institut "Ruđer Bošković", Zagreb,
Fakultet kemijskog inženjerstva i tehnologije, Zagreb

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus


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