The NMR Study of Products Obtained by Photorearrangement of Pyridinium Salts (CROSBI ID 629469)
Prilog sa skupa u zborniku | sažetak izlaganja sa skupa | domaća recenzija
Podaci o odgovornosti
Blažek Bregović, Vesna ; Basarić, Nikola
engleski
The NMR Study of Products Obtained by Photorearrangement of Pyridinium Salts
Light induced molecular changes are important in chemistry, biochemistry and medicine. Namely, photochemical reactions can induce transformation of molecules resulting in completely different chemical behavior and biological activity of the products. Pyridinium salts are present in the structure in NAD+ and NADP+ cofactors, which are essential for functioning of all living cells. Moreover, pyridinium derivatives are photochemicaly reactive, 1, 2 which in principle enables activation or deactivation of biochemical processes involving NAD+ and NADP+ cofactors. Therefore, a deeper understanding of photophysical transformation of pyridinium salts is of great relevance and could redirect future studies in life sciences.3 Herein we present systematic investigations of photochemistry of o-, m- and p-methyl substituted N-metyhlpyridinium salts. NMR spectroscopy was used to reveal complex structures of the rearranged products.
N-metyhlpyridinium salts ; photochemistry ; NMR spectroscopy
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Podaci o prilogu
32-32.
2015.
objavljeno
Podaci o matičnoj publikaciji
met4pharm - Pharma NMR Conference / Rovinj - Crveni Otok, Hrvatska
Podaci o skupu
Pharma NMR Conference / Application of NMR Spectroscopy in Pharamaceutical Industry
poster
23.11.2015-25.11.2015
Rovinj, Hrvatska