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Chemical and Thermal Properties of Cellulose Acetate Prepared from White Willow (Salix alba) and Black Alder (Alnus glutinosa) as a Potential Polymeric Base of Biocomposite Materials (CROSBI ID 221863)

Prilog u časopisu | izvorni znanstveni rad | međunarodna recenzija

Španić, Nikola ; Jambreković, Vladimir ; Medved, Sergej ; Antonović, Alan Chemical and Thermal Properties of Cellulose Acetate Prepared from White Willow (Salix alba) and Black Alder (Alnus glutinosa) as a Potential Polymeric Base of Biocomposite Materials // Chemical and biochemical engineering quarterly, 29 (2015), 3; 357-365. doi: 10.15255/CABEQ.2015.2176

Podaci o odgovornosti

Španić, Nikola ; Jambreković, Vladimir ; Medved, Sergej ; Antonović, Alan

engleski

Chemical and Thermal Properties of Cellulose Acetate Prepared from White Willow (Salix alba) and Black Alder (Alnus glutinosa) as a Potential Polymeric Base of Biocomposite Materials

Natural polymeric materials are an interesting alternative to petrochemical products with potential application in almost all areas of human activity. Wishing to expand the field of cellulose acetate application to the biocomposite wood materials, the possibilities of cellulose isolation and its acetylation from two domestic, commercially meagrely used, wood species was investigated in this paper. Cellulose isolated from white willow (Salix alba) and black alder (Alnus glutinosa) was acetylated using acetic anhydride and perchloric acid catalyst, by treatment at room temperature for 45 minutes. Analysis of the laboratory acetylation process, beside chemical analysis of the gained product by infrared spectroscopy (FT-IR), indicated the impact of hemicelluloses, present both in cellulose and cellulose acetate structure, on values of mass increase, number of acetyl groups and the degree of substitution. Results of thermogravimetric analysis (TGA) later confirmed the statement that thermal properties of cellulose acetate were also dependant on hemicelluloses.

Wood ; Cellulose ; Acetylation ; Bio Composite materials ; FT-IR ; TGA

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Podaci o izdanju

29 (3)

2015.

357-365

objavljeno

0352-9568

10.15255/CABEQ.2015.2176

Povezanost rada

Kemijsko inženjerstvo, Drvna tehnologija

Poveznice
Indeksiranost